Authors unavailable · Energy Storage Materials · 2021
To review 2D conducting MOFs for electrochemical energy storage, emphasising their structural motifs, electronic-conduction mechanisms, conductivity-improvement strategies, battery and supercapacitor applications, and the role of advanced characterisation, especially NMR, in resolving charge-storage mechanisms.
The review’s argument is preserved as a navigable set of section summaries.
Reviews selected Li-ion, Li-S, Na-ion, Na-I2, Zn-ion and supercapacitor demonstrations, culminating in Table 1 comparative benchmarks.
Relevance: Core · p004 · Potential Energy Storage Applications of 2D Conducting MOFs · Fig. 5-Fig. 11; Table 1
Explains why conducting MOFs are attractive for LIBs, SIBs, ZIBs, Li-S systems and supercapacitors while noting ion-size, shuttle, cathode and stability challenges.
Relevance: Core · p003 · 2D conducting MOFs in EES: Challenges and remedies
Synthesises consensus advantages and open problems: immature practical implementation, insufficient mechanistic work, interlayer transport, redox-active linker diversity and scale-up.
Relevance: Core · p008 · Conclusions and Perspectives
Defines layered graphite-like 2D MOF structures, metal-node/linker motifs, pore architecture and early high-conductivity Ni3(HITP)2 history.
Relevance: Core · p001 · Fundamentals and History of 2D conducting MOFs · Fig. 2
Frames EES needs, contrasts 2D conducting MOFs with conventional MOFs, and states the review's emphasis on structure-property-performance relationships and NMR.
Relevance: Core · p001 · Introduction
Compares ex-situ, in-situ and operando characterisation; argues that NMR can resolve ion dynamics, pore-volume overestimation and molecular interactions not captured by bulk methods alone.
Relevance: Core · p007 · Advanced characterization techniques and importance of Nuclear Magnetic Resonance (NMR) · Fig. 12; Fig. 13
Summarises charge-transport factors and introduces mechanism classes including protracted conjugation, through-bond, through-space, hopping and guest-promoted pathways.
Relevance: Core · p002 · Origin of electrical conductivity in MOFs · Fig. 3
Organises design approaches around linker/metal choice, thin-film and nanosheet formation, dopants, carbon hybrids and conducting-polymer loading.
Relevance: Core · p003 · Strategies to improve the conductivity in 2D MOFs · Fig. 4
Classification systems are attributed to this review and are not treated as a global material registry.
The NMR section distinguishes measurements after disassembly from measurements in assembled cells and during active cycling, highlighting different access to side reactions and metastable phases.
Categories: ex-situ · in-situ · operando
p007 · Advanced characterization techniques and importance of NMR
Figure 4 and the accompanying section organise conductivity enhancement around linker selection, guest/dopant incorporation, carbon hybridisation and conducting-polymer pathways.
Categories: organic ligands · dopants/guests · carbon-based composites · conducting polymers
p010 · Strategies to improve the conductivity in 2D MOFs · Fig. 4
The review separates applications by electrochemical storage chemistry and uses those categories to discuss different transport and redox problems.
Categories: Li-ion batteries · Li-S batteries · Na-ion batteries · Na-I2 batteries · Zn-ion batteries · supercapacitors
p004 · Potential Energy Storage Applications of 2D Conducting MOFs
The review contrasts early EDL-dominant Ni3(HITP)2 work with later redox-active HAB and Cu-DBC frameworks that combine ligand/metal redox with double-layer storage.
Categories: electric double layer capacitance · pseudocapacitance · mixed EDL and redox contribution
p006 · Supercapacitors · Fig. 11
The review explicitly classifies conductive behaviour by whether delocalisation occurs through pi-d conjugation, coordination bonds, interlayer or intermolecular pi-pi contacts, hopping between redox sites, or guest/framework conduction pathways.
Categories: extended conjugation · through bonds · through space · redox hopping · guest promoted hopping
p009 · Figures and tables · Fig. 3
Review-defined families retain their representative materials and conduction descriptions.
Sulfur-rich 2D MOFs based on BHT or related dithiolene/thiolate linkers that create strong metal-sulfur coupling and high conductivity.
Conduction: Soft sulfur linkers and metal-sulfur orbital overlap can produce high electrical conductivity and, in selected films, band-like transport.
Representative materials: Cu-BHT · Ag3BHT2 · Fe3(THT)2(NH4)3
Nodes / linkers: Cu · Ag · Fe · benzenehexathiol · triphenylenehexathiol · dithiolene
p002 · Origin of electrical conductivity in MOFs
Conductive 2D MOFs using HAB linkers to create dense redox-active skeletons.
Conduction: Dense redox centres and electronic conduction support high-power sodium storage and pseudocapacitive charge storage.
Representative materials: Co-HAB · Cu-HAB · Ni-HAB
Nodes / linkers: Co · Cu · Ni · hexaaminobenzene
p005 · Na-ion batteries · Fig. 9
Layered 2D MOFs built from planar triphenylene-derived ligands such as HITP or HHTP coordinated to square-planar metal nodes.
Conduction: In-plane pi-d conjugation and stacked-layer channels support electronic conduction and electrolyte-ion motion.
Representative materials: Ni3(HITP)2 · Cu3(HHTP)2 · Cu-HITP · Cu-THQ
Nodes / linkers: Ni · Cu · hexaiminotriphenylene · hexahydroxytriphenylene · tetrahydroxyquinone
p001 · Fundamentals and History of 2D conducting MOFs · Fig. 2
Hybrid electrodes combining conducting MOFs with CNTs, graphene, carbon fibres or related carbon scaffolds.
Conduction: Carbon components bridge layers, improve electron percolation and shorten ion-diffusion paths.
Representative materials: S@Ni3(HITP)2-CNT · Ni-MOF/C-CNTs · Ni-CAT/CNF · Cu-CAT/NWAs
Nodes / linkers: Ni · Cu · Co · HITP · catecholate · HHTP
p003 · Hybridization with carbon-based materials · Fig. 4
Fully conjugated phthalocyanine-based 2D MOFs with copper coordination sites and tunable secondary metal nodes.
Conduction: Conjugated phthalocyanine sheets and polarising metal centres support polyiodide adsorption and mixed capacitive/diffusion storage.
Representative materials: Fe2-O8-PcCu · Zn2-O8-PcCu · Ni2-O8-PcCu
Nodes / linkers: Fe · Zn · Ni · Cu · octahydroxy phthalocyanine · polyphthalocyanine
p005 · Na-I2 batteries · Fig. 10
2D conducting frameworks where non-innocent quinone/semiquinoid ligands contribute directly to charge storage.
Conduction: Charge storage and transport arise from coupled metal-node and redox-active ligand processes rather than metal centres alone.
Representative materials: Cu-THQ · MOF 1 · MOF 2 · Cu-DBC
Nodes / linkers: Cu · Fe · tetrahydroxyquinone · dichlorodihydroxybenzoquinone · dibenzochrysene-octaol
p004 · Li-ion Batteries · Fig. 6
Review-level synthesis principles remain separate from primary-study recipes.
Combine 2D conducting MOFs with graphene, CNTs, carbon nanofibres, carbon onions, graphene oxide or carbon-paste electrodes.
Claimed effects: Bridges stacked layers, enhances vertical charge conduction and can improve capacity and rate performance.
Controlling variables: carbon scaffold type · interlayer bridge formation · electrode microstructure · ion-diffusion path length
Representative materials: Ni-MOF/C-CNTs · S@Ni3(HITP)2-CNT · Ni-CAT/CNF
Caveat: Composite performance cannot be attributed to the MOF alone without primary-paper controls.
p003 · Hybridization with carbon-based materials
Polymerise or load conducting polymers in MOF pores so polymer chains or clusters provide delocalised charge pathways.
Claimed effects: Can increase conductivity by creating electron pathways through the framework while retaining crystalline MOF structure in the cited example.
Controlling variables: monomer uptake · oxidative polymerisation · framework crystallinity retention · host-guest interactions
Representative materials: PPy-loaded fluorescent MOF
Caveat: The review's cited-reference mapping for this example should be checked against the primary paper before using it quantitatively.
p003 · Loading with conducting polymers
Introduce electroactive guest molecules, cations, metal oxides, nanoclusters or redox molecules into MOF voids to create additional charge pathways.
Claimed effects: Can add redox-active sites and new conduction channels, but guest inclusion can reduce or eliminate accessible porosity.
Controlling variables: guest identity · post-synthetic versus in-synthesis loading · pore blockage · redox-active site density
Representative materials: KAUST-7' · TCNQ-doped frameworks · CoSNC derived from PPF-3 nanosheets
Caveat: The review warns that bulky guests can truncate porosity and therefore may trade conductivity for ion accessibility.
p003 · Incorporation of dopants · Fig. 4
Cast conducting MOFs as crystalline or self-standing thin films at interfaces to enhance continuity, morphology and device relevance.
Claimed effects: Can yield high-conductivity thin films and allow Hall or terahertz measurements of mobility and band-like transport.
Controlling variables: interface chemistry · solvent pair · film continuity · ambient atmosphere · metal and thiol linker selection
Representative materials: Cu-BHT · Fe3(THT)2(NH4)3 · Ag3BHT2
Caveat: Thin-film values are review-reported secondary benchmarks and depend strongly on film morphology and measurement geometry.
p002 · Origin of electrical conductivity in MOFs
Choose planar, conjugated, chelating linkers and compatible metal nodes to generate ordered 2D charge-transport pathways.
Claimed effects: Improves charge delocalisation and can create regular transport paths through metal-ligand chains or pi-d conjugation.
Controlling variables: linker symmetry · chelating functional group · metal-node identity · metal-ligand orbital overlap
Representative materials: Mn2(DSBDC)(DMF)2 · Ni3(HITP)2 · Cu3(HHTP)2
Caveat: The review treats this at concept level; primary papers are needed to confirm exact conductivity and structural assignments.
p003 · Specific Linkers
Use templates or sacrificial MOF precursors to suppress crystal growth in one direction and generate ultrathin 2D MOF or MOF-derived heterostructures.
Claimed effects: Promotes 2D nanosheet morphology and can integrate higher-conductivity supports or derived phases.
Controlling variables: template chemistry · growth directionality · graphene sheet integration · post-synthetic sulfidation
Representative materials: nickel-squarate MOF nanosheets · 2D Ni-MOF/graphene nanosheet stacks · 2D nickel sulfide/GNS heterostructure
Caveat: The MOF can become a precursor or sacrificial template, so final electrode chemistry may no longer be a pristine MOF.
p003 · Loading with conducting polymers
Use delamination or ball milling to produce ultrathin nanosheets from layered conductive MOFs.
Claimed effects: Exposes more active sites, shortens ion-diffusion paths and improves processability for micro-supercapacitors.
Controlling variables: layer thickness · crystallinity · mechanical exfoliation conditions · solution processability
Representative materials: HHB-Cu nanosheets · HHTP-Cu nanosheets · Ni2(CuPc(NH)8) nanosheets
Caveat: Exfoliation benefits are coupled to carbon additives in some device demonstrations.
p002 · Origin of electrical conductivity in MOFs
These are the review authors’ synthesis, not newly measured results.
The review treats 2D conducting MOFs as a distinct subset of 2D MOFs because their elevated conductivity and transport pathways differ from conventional low-conductivity MOFs.
Evidence basis: review_reasoning
Caveat: The boundary is conceptual and material-specific rather than a single conductivity threshold.
p001 · Introduction
The review states that few studies provide in-depth investigation of charge-transport mechanisms in MOFs, limiting mechanistic certainty.
Evidence basis: review_reasoning
Caveat: This is the review authors' assessment of the literature up to 2020.
p002 · Origin of electrical conductivity in MOFs
Guest-promoted transport can create conduction pathways, but bulky guest inclusion may block pores and reduce or eliminate porosity.
Evidence basis: review_reasoning
Caveat: Important for interpreting conductivity improvements in energy-storage electrodes where ion access remains essential.
p002 · Guest-Promoted Transport · Fig. 3
The review cautions that band-like and hopping transport can be hard to distinguish in polycrystalline MOFs because defects and grain boundaries obscure intrinsic behaviour.
Evidence basis: review_reasoning
Caveat: Applies especially to polycrystalline samples and lower-temperature transport analysis.
p002 · Redox Hopping
The review suggests that most conductivity improvement has been in-plane and that tuning the interlayer gap could promote out-of-plane charge conduction.
Evidence basis: review_reasoning
Caveat: Presented as a perspective rather than a demonstrated design rule.
p008 · Conclusions and Perspectives
A typical 2D conducting MOF consists of coordinated organic linkers and metal nodes forming layered lattices with open nanochannels between pi-stacked sheets.
Evidence basis: review_reasoning
Caveat: The description generalises common frameworks; individual stacking and pore symmetry vary with linker and metal selection.
p001 · Fundamentals and History of 2D conducting MOFs · Fig. 2
Planar conjugated linkers with ortho-substituted donor groups and transition-metal nodes promote square-planar coordination, pi-d hybridisation and in-plane charge delocalisation.
Evidence basis: multi_reference
Caveat: The review does not deeply analyse band structures; it points readers to specialist conductivity reviews.
p001 · Fundamentals and History of 2D conducting MOFs
For Li-S batteries, the review argues that 2D conducting MOFs can act as sulfur hosts with active binding sites and conductivity that help suppress polysulfide dissolution and improve utilisation.
Evidence basis: multi_reference
Caveat: The review mixes computational and composite-electrode evidence; primary-paper details are needed for quantitative conclusions.
p005 · Li-Sulphur batteries · Fig. 7; Fig. 8
The review highlights Ni-HITP as a LIB example where both anions and cations participate in charge storage, implying that anion conductivity as well as cation conductivity can matter.
Evidence basis: single_reference
Caveat: This is based on one highlighted demonstration and should not be generalised to all 2D conducting MOF cathodes.
p004 · Li-ion Batteries · Fig. 5
The review argues that XPS, XRD, electron microscopy and gas adsorption are insufficient by themselves to resolve molecular ion-electrode interactions and pore-volume effects in working EES electrodes.
Evidence basis: multi_reference
Caveat: The review also states that NMR faces sensitivity and resolution challenges in conductive/composite materials.
p007 · Advanced characterization techniques and importance of NMR · Fig. 13
Extended pi-d conjugation in 2D planes is presented as an overriding mechanism for enhanced conductivity in many conducting MOFs.
Evidence basis: multi_reference
Caveat: The review also notes interlayer pi-pi interactions and redox effects, so this mechanism should not be assumed exclusive.
p002 · Protracted conjugation · Fig. 3
Non-innocent organic linkers can add ligand redox capacity alongside metal-node redox activity, increasing charge-storage capability.
Evidence basis: multi_reference
Caveat: The review notes that only a few redox-active materials are currently known.
p004 · Li-ion Batteries · Fig. 6
The review positions Na-ion batteries using 2D conducting MOFs as promising but still at an early stage compared with Li-ion work.
Evidence basis: review_reasoning
Caveat: The review also notes general SIB issues such as larger Na-ion size and dendrite/safety concerns.
p004 · 2D conducting MOFs in EES: Challenges and remedies
The review interprets later HAB and Cu-DBC supercapacitor results as showing that redox-active ligands and metal centres can move 2D MOF supercapacitors beyond simple EDL storage.
Evidence basis: multi_reference
Caveat: Early EDL capacitance in Ni3(HITP)2 was described as not very impressive and redox-active mechanisms were initially overlooked.
p006 · Supercapacitors · Fig. 11
Every row remains visibly secondary and links to a primary dossier only where the mapping is verified.
| Material | Property | Reported value | Context and quality | Primary evidence | Review source |
|---|---|---|---|---|---|
| SecondaryCo-HAB | specific capacity | 214 mA h g-1 in 7 min | Na-ion battery; high-rate benchmark described in text Text · Exact Reported | research_0004 | p005 · Na-ion batteries · Fig. 9; Table 1 |
| SecondaryCu3(HHTP)2 | reversible capacity | 228 mA h g-1 at 50 mA g-1 | Rechargeable aqueous ZIB in 3.0 M Zn(CF3SO3)2 Text · Exact Reported | research_0188 | p005 · Zn-ion batteries · Table 1 |
| SecondaryCu-BHT | electrical conductivity | ~1580 S cm-1 | Experimental room-temperature conductivity; discussed as Li-S host material Text · Approximate | No verified corpus mapping | p005 · Li-Sulphur batteries · Fig. 7; Table 1 |
| SecondaryCu-DBC | gravimetric capacitance and energy density | 479 F g-1 at 0.2 A g-1; 13.8 W h kg-1 at 0.1 kW kg-1 | Supercapacitor electrode; symmetric solid-state device energy density also reported Text · Exact Reported | research_0068 | p006 · Supercapacitors · Fig. 11; Table 1 |
| SecondaryCu-THQ | specific capacity and energy density | 387 mA h g-1; 775 Wh kg-1 | Rechargeable LIB cathode; Table 1 reports energy density 775 Wh kg-1 Table · Exact Reported | No verified corpus mapping | p015 · Figures and tables · Table 1 |
| SecondaryFe2-O8-PcCu/I2 | capacity retention | 157 mA h g-1 at 1.5 A g-1; ~100% retention at 0.3 A g-1 over 100 cycles | Na-I2 battery electrode at high current density Text · Exact Reported | No verified corpus mapping | p005 · Na-I2 batteries · Fig. 10; Table 1 |
| SecondaryFe3(THT)2(NH4)3 | room-temperature mobility | up to ca. 220 cm2 V-1 s-1 | Thin film characterised by Hall effect and high-frequency terahertz photoconductivity Text · Approximate | research_0001 | p002 · Origin of electrical conductivity in MOFs |
| SecondaryMOF 1 | electrical conductivity and capacity | 2.6 x 10-3 S cm-1; 141 mA h g-1 | Semiquinoid-based LIB cathode; 141 mA h g-1 at high charging rate reported in text Text · Exact Reported | No verified corpus mapping | p004-p005 · Li-ion Batteries · Table 1 |
| SecondaryNi3(HITP)2 | gravimetric capacitance | 111 F g-1; >90% capacity retention over 10000 cycles | EDL supercapacitor in TEABF4/ACN electrolyte; low discharge rate 0.05 A g-1 Text · Exact Reported | No verified corpus mapping | p006 · Supercapacitors · Table 1 |
| SecondaryNi-HAB | gravimetric capacitance | 420 F g-1; ~90% retention over 12000 cycles | Submillimetre-thick electrochemical supercapacitor in 1 M KOH Text · Exact Reported | No verified corpus mapping | p006 · Supercapacitors · Table 1 |
| SecondaryNi-HITP | specific capacity | 155 mA h g-1 | LIB cathode; 10 mA g-1; review-reported Table 1/text value Table · Exact Reported | No verified corpus mapping | p015 · Figures and tables · Table 1 |
| SecondaryNi2(CuPc(NH)8) nanosheets with exfoliated graphene | areal capacitance | 18.9 mF cm-2 | Micro-supercapacitor fabricated with exfoliated graphene Text · Exact Reported | research_0006 | p006 · Supercapacitors |
| SecondaryS@Ni3(HITP)2-CNT | specific capacity | 1302.9 mA h g-1 at 0.2 C | Li-S cathode composite at 0.2 C Text · Exact Reported | No verified corpus mapping | p005 · Li-Sulphur batteries · Fig. 8; Table 1 |
Open questions are presented as review-author priorities, not conclusions from the primary database.
Conductivity has mainly improved in-plane; out-of-plane/interlayer conduction remains an opportunity.
Proposed direction: Tune interlayer gap and pi-electron overlap between consecutive layers.
p008 · Conclusions and Perspectives
Effective ion transport is recognised as important for fast charging, but Li-ion storage mechanisms and coupled ionic/electronic transport in 2D conducting MOF cathodes remain insufficiently understood.
Proposed direction: Study Li-ion storage mechanisms together with ionic and electronic transport properties in next-generation MOF cathodes.
p005 · Li-ion Batteries
Few studies provide in-depth mechanistic investigation of charge transport in MOFs, making it hard to state transport mechanisms definitively.
Proposed direction: Combine variable-temperature conductivity, electronic-structure calculations, optical spectroscopy and device measurements.
p002 · Origin of electrical conductivity in MOFs
Very limited advanced studies, including NMR, have been used to study ion dynamics, pore volume and nanopore effects on charge storage.
Proposed direction: Use in-situ, operando and solid-state NMR alongside diffraction, spectroscopy and modelling.
p008 · Conclusions and Perspectives
The review states that more redox-active organic linkers are needed and only a few redox-active materials are currently known.
Proposed direction: Design and screen additional redox-active planar organic linkers that preserve conductivity and porosity.
p008 · Conclusions and Perspectives
Limited MOF yield is presented as a serious concern for commercial application at large scale.
Proposed direction: Develop production technologies for scalable synthesis and electrode assembly.
p008 · Conclusions and Perspectives
Na-ion battery research using 2D conducting MOF electrodes is described as still in its infancy.
Proposed direction: Develop robust 2D conducting MOF electrodes with pore sizes and redox sites suited to Na-ion transport and stability.
p004 · 2D conducting MOFs in EES: Challenges and remedies
Although 2D conducting MOF cathodes are promising for ZIBs, the review says they have rarely been explored.
Proposed direction: Explore compatible pore sizes, layer gaps and redox-active frameworks for aqueous Zn2+ insertion/extraction.
p005 · Zn-ion batteries
Mappings show which printed review references have a verified counterpart in the frozen primary corpus.
| Reference | Study | Role and context | Corpus mapping |
|---|---|---|---|
| Ref. 552020 | Electrically Conductive Metal-Organic Frameworks | transport_mechanism · background_reviewCited for conductive-MOF fundamentals and the Fig. 3 mechanism taxonomy reproduced or summarised by this review. | Unmapped |
| Ref. 702018 | High-mobility band-like charge transport in a semiconducting two-dimensional metal-organic framework | transport_benchmark · thin_filmUsed as the review's high-mobility thin-film example with Hall and terahertz evidence for band-like transport. | research_0001 |
| Ref. 732017 | Conductive MOF electrodes for stable supercapacitors with high areal capacitance | historical_development · supercapacitor_benchmarkHighlighted as a pioneering Ni3(HITP)2 supercapacitor demonstration and used in Table 1. | Unmapped |
| Ref. 772018 | Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal-Organic Framework | material_family · synthesis_strategyCited in the fundamentals section for linker symmetry and honeycomb lattice formation in 2D conducting MOFs. | research_0792 |
| Ref. 792020 | 2D Conductive Metal-Organic Frameworks: An Emerging Platform for Electrochemical Energy Storage10.1002/anie.202006102 | battery_benchmark · redox_active_ligandUsed by the review for Cu-THQ Li-ion storage, redox-active ligand/metal-node charge storage and Figure 6. | Unmapped |
| Ref. 842014 | High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal-Organic Graphene Analogue | transport_benchmark · historical_developmentSupports the review's historical discussion of high-conductivity Ni3(HITP)2 as a graphene analogue. | Unmapped |
| Ref. 852015 | A two-dimensional π-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour | transport_mechanism · nanosheet_deviceUsed by the review for pi-d conjugation and a nanosheet micro-supercapacitor example. | research_0006 |
| Ref. 1082018 | Highly Conductive 2D Metal-Organic Framework Thin Film Fabricated by Liquid-Liquid Interfacial Reaction Using One-Pot-Synthesized Benzenehexathiol | synthesis_strategy · thin_filmCited as a liquid-liquid interfacial route to highly conductive BHT-based MOF thin films. | research_0096 |
| Ref. 1102018 | An overview of different strategies to introduce conductivity in metal-organic frameworks and miscellaneous applications thereof | strategy_taxonomy · background_reviewUsed as the source for Figure 4's strategy flowchart for conductivity enhancement. | Unmapped |
| Ref. 1112015 | Million-fold electrical conductivity enhancement in Fe2 (DEBDC) versus Mn2 (DEBDC)(E= S, O) | specific_linker_strategy · transport_benchmarkCited in the selective-linker section for conductivity enhancement from sulfur/oxygen linker substitution and metal-ligand pathways. | research_0063 |
| Ref. 1142019 | Shape-Assisted 2D MOF/Graphene Derived Hybrids as Exceptional Lithium-Ion Battery Electrodes | template_growth · carbon_hybridCited for template/shape-assisted 2D MOF-graphene heterostructure formation and derived battery electrodes. | Unmapped |
| Ref. 1182018 | Multielectron-Transfer-based Rechargeable Energy Storage of Two-Dimensional Coordination Frameworks with Non-Innocent Ligands | battery_benchmark · redox_active_ligandUsed for the first highlighted LIB cathode example and Table 1 benchmark. | Unmapped |
| Ref. 1192020 | Effects of Covalency on Anionic Redox Chemistry in Semiquinoid-Based Metal-Organic Frameworks | battery_benchmark · redox_active_ligandUsed for semiquinoid Fe-framework conductivity and LIB capacity comparison. | Unmapped |
| Ref. 1202019 | Cellulose Nanofiber @ Conductive Metal-Organic Frameworks for High-Performance Flexible Supercapacitors | conducting_polymer_strategy · flexible_supercapacitorThe review cites Ref. 120 in the conducting-polymer loading paragraph; the bibliography entry itself appears to describe cellulose nanofiber@MOF flexible supercapacitors. | research_0174 |
| Ref. 1272020 | Fully Conjugated Phthalocyanine Copper Metal-Organic Frameworks for Sodium-Iodine Batteries with Long-Time-Cycling Durability | na_iodine_battery · benchmarkUsed for fully conjugated phthalocyanine MOFs as Na-I2 cathodes and metal-node-dependent polyiodide adsorption. | Unmapped |
| Ref. 1322019 | Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries | zinc_ion_battery · benchmarkUsed for Cu3(HHTP)2 as an aqueous ZIB cathode and Table 1 performance benchmark. | research_0188 |
| Ref. 1412018 | Novel Conductive Metal-Organic Framework for a High-Performance Lithium-Sulfur Battery Host: 2D Cu-Benzenehexathial (BHT) | li_sulphur_battery · conductivity_benchmarkUsed for the first-principles and conductivity discussion of Cu-BHT as a Li-S sulfur host. | Unmapped |
| Ref. 1422019 | A Highly Conductive MOF of Graphene Analogue Ni3(HITP)2 as a Sulfur Host for High-Performance Lithium-Sulfur Batteries | li_sulphur_battery · composite_benchmarkUsed for Ni3(HITP)2-CNT as a conductive Li-S sulfur host with high review-reported capacity. | Unmapped |
| Ref. 1432018 | Stabilization of Hexaaminobenzene in a 2D Conductive Metal-Organic Framework for High Power Sodium Storage | sodium_ion_battery · benchmarkUsed for Co-HAB high-power sodium storage and the review's Na-ion benchmark discussion. | research_0004 |
| Ref. 1462017 | Conductive Metal-Organic Framework Nanowire Array Electrodes for High-Performance Solid-State Supercapacitors | supercapacitor_benchmark · nanowire_arrayUsed for conductive MOF nanowire arrays in solid-state supercapacitors. | research_0026 |
| Ref. 1472018 | Robust and conductive two-dimensional metal-organic frameworks with exceptionally high volumetric and areal capacitance | supercapacitor_benchmark · redox_active_ligandUsed for dense HAB MOF supercapacitors with high gravimetric, volumetric and areal capacitance. | Unmapped |
| Ref. 1482020 | Conjugated Copper-Catecholate Framework Electrodes for Efficient Energy Storage | supercapacitor_benchmark · mixed_edl_pseudocapacitanceUsed for Cu-DBC supercapacitor performance and mixed EDL/pseudocapacitive mechanism. | research_0068 |
| Ref. 1492020 | Molecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes | simulation · supercapacitor_mechanismUsed for molecular dynamics modelling of EDL charging dynamics in 2D conducting MOF supercapacitors. | Unmapped |
| Ref. 1572015 | NMR Study of Ion Dynamics and Charge Storage in Ionic Liquid Supercapacitors | nmr · ion_dynamicsCited for NMR's ability to probe ion dynamics and pore-volume interpretation in EES materials. | Unmapped |
| Ref. 1582020 | Insight into the structures and dynamics of organic semiconductors through solid-state NMR spectroscopy | solid_state_nmr · characterisationUsed for NMR timescale/lengthscale context and solid-state NMR characterisation discussion. | Unmapped |