Chen I.-F., Lu C.-F., Su W.-F. · Langmuir · 2018 · 15754-15762
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Ag3BHT2 thin film is proposed as a potential material for electronic devices and sensors because of its high conductivity and simple synthesis.
Caveat: No actual device or sensor performance test is reported in this paper.
15754 and 15760 · Abstract; Conclusions · Linked to 1 structured result
Ag3BHT2 thin film conductivity is attributed to Ag-S pi-d conjugation plus an ordered hexagonal planar structure that supports intralayer and interlayer charge transport.
Caveat: Mechanistic attribution is supported by XRD/XPS correlations rather than direct transport pathway measurement.
15757-15760 · Materials Characterization · Figure 6; Table 2 · Linked to 3 structured results
Ag3BHT2 interfacial thin film is more conductive than the powder-pressed thick film because it is more ordered and has fewer uncoordinated BHT/sulfur defects.
Caveat: The thick-film defect assignment comes mainly from surface-sensitive XPS plus weak XRD intensity.
15758-15760 · Materials Characterization · Figures 5-7; Table 2 · Linked to 4 structured results
The one-pot BHT synthesis avoids liquid ammonia and is safer, simpler, and faster than the conventional route, with the best C6F6/i-C3H7-SNa route giving 85% yield in 6 h.
Caveat: Safety comparison is argued qualitatively; yield/time are directly tabulated.
15755 and 15760 · Results and Discussion; Conclusions · Table 1 · Linked to 1 structured result
Au3BHT2 is nearly insulating because its structure is disordered/randomly oriented and lacks effective planar conjugation and pi-pi stacking.
Caveat: The structural interpretation is inferred from weak XRD, XPS oxidation-state complexity, and morphology.
15758-15760 · Materials Characterization; Conclusions · Figure 6; Table 2 · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Ag3BHT2 | Ag3BHT2Ag ions · benzenehexathiol (BHT) | 2D · PristineHexagonal lattice planar structure; one BHT molecule coordinates six metal ions and each metal ion coordinates four sulfurs. | 15756-15758 · Results and Discussion · Scheme 2; Figure 6 |
| Au3BHT2 | Au3BHT2Au ions · benzenehexathiol (BHT) | 2D · PristineNominal 2D planar BHT-Au coordination polymer; experimentally lower crystallinity and disordered/deviated planar structure. | 15758-15760 · Results and Discussion · Figure 6 |
| benzenehexathiol | C6S6H6none · benzenehexathiol (BHT) | 0D · UnknownOrganic thiol precursor ligand; not a conductive MOF. | 15760 · Experimental Methods - Synthesis of Benzenehexathiol (BHT) |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Ag3BHT2 powder-pressed thick filmresearch_0096__mat__ag3bht2 | Pellet · Target Sample · Pristine Framework | MOF powder filtered, washed, vacuum dried, then pressed into 7 mm disk at 50 psi64.23 +/- 0.43 um | 15759-15761 · Table 2; Experimental Methods · Table 2 |
| Ag3BHT2 thin filmresearch_0096__mat__ag3bht2 | Thin Film · Target Sample · Pristine Framework | liquid-liquid interfacial film deposited by slow liquid removal onto Si/SiO2 substrate20 x 20 mm2 silicon substrate with 300 nm thermally grown SiO2 · 276.51 +/- 5.53 nm | 15759-15761 · Table 2; Experimental Methods · Table 2 |
| Au3BHT2 powder-pressed thick filmresearch_0096__mat__au3bht2 | Pellet · Target Sample · Pristine Framework | MOF powder filtered, washed, vacuum dried, then pressed into 7 mm disk at 50 psi89.05 +/- 0.12 um | 15759-15761 · Table 2; Experimental Methods · Table 2 |
| Au3BHT2 thin filmresearch_0096__mat__au3bht2 | Thin Film · Target Sample · Pristine Framework | liquid-liquid interfacial film deposited by slow liquid removal onto Si/SiO2 substrate20 x 20 mm2 silicon substrate with 300 nm thermally grown SiO2 · 324.72 +/- 11.23 nm | 15759-15761 · Table 2; Experimental Methods · Table 2 |
| BHT yellow solidresearch_0096__mat__bht_ligand | Powder · Unknown · Unknown | precipitated, filtered, washed with water and acetone | 15760 · Experimental Methods - Synthesis of Benzenehexathiol (BHT) |