Copper-cobalt bimetallic conductive metal–organic frameworks as bifunctional oxygen electrocatalyst in alkaline and neutral media
Zhang M.-C., Liu M.-Y., Yang M.-X. et al. · Journal of Solid State Chemistry · 2023
Reported here: CuCo-HITP
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2 papers
Zhang M.-C., Liu M.-Y., Yang M.-X. et al. · Journal of Solid State Chemistry · 2023
Reported here: CuCo-HITP
Chen T., Dou J.-H., Yang L. et al. · Journal of the American Chemical Society · 2020
Reported here: (Co0.51Cu2.49)(HITP)2 · (Co0.71Cu2.29)(HITP)2 · (Co1.09Cu1.91)(HITP)2 · (Co1.59Cu1.41)(HITP)2 · (Co1.83Cu1.17)(HITP)2 · (Co2.47Cu0.53)(HITP)2
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| CuCo-HITP2023 · Copper-cobalt bimetallic conductive metal–organic frameworks as bifunctional oxygen electrocatalyst in alkaline and neutral media | CuCo-HITP; mixed Cu/Co analogue of Cu3(HITP)2, exact empirical formula not reportedCu and Co ions coordinated by M-N4 sites; text describes Cu2+ and Co2+ incorporation, with XPS showing Cu+/Cu2+ and Co2+/Co3+ components. · HITP = 2,3,6,7,10,11-hexaiminotriphenylene | 2D · PristineBimetallic two-dimensional porous conductive MOF similar to Cu3(HITP)2, formed by simultaneous Cu/Co coordination to HITP ligands with some Cu sites replaced by Co. | main p.2 · Results and discussion - Material characterization · Fig. 1 |
| (Co0.51Cu2.49)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys | Co0.51Cu2.49(HITP)2Co0.51Cu2.49 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene | 2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends. | 12369-12370 · Results and Discussion · Figures 2b, 5; Table S5 |
| (Co0.71Cu2.29)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys | Co0.71Cu2.29(HITP)2Co0.71Cu2.29 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene | 2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends. | 12369-12370 · Results and Discussion · Figures 2b, 5; Table S5 |
| (Co1.09Cu1.91)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys | Co1.09Cu1.91(HITP)2Co1.09Cu1.91 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene | 2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends. | 12369-12370 · Results and Discussion · Figures 2b, 5; Table S5 |
| (Co1.59Cu1.41)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys | Co1.59Cu1.41(HITP)2Co1.59Cu1.41 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene | 2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends. | 12369-12370 · Results and Discussion · Figures 2b, 5; Table S5 |
| (Co1.83Cu1.17)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys | Co1.83Cu1.17(HITP)2Co1.83Cu1.17 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene | 2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends. | 12369-12370 · Results and Discussion · Figures 2b, 5; Table S5 |
| (Co2.47Cu0.53)(HITP)22020 · Continuous Electrical Conductivity Variation in M3(Hexaiminotriphenylene)2(M = Co, Ni, Cu) MOF Alloys | Co2.47Cu0.53(HITP)2Co2.47Cu0.53 · HITP = 2,3,6,7,10,11-hexaiminotriphenylene | 2D · PristineLayered electrically conducting MOF; synchrotron PXRD Pawley refinements fit orthorhombic Cmcm for pure M3(HITP)2; alloys are isostructural solid solutions following Vegard-type trends. | 12369-12370 · Results and Discussion · Figures 2b, 5; Table S5 |