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1 papers
Zhang T., Si C., Guo K. et al. · Inorganic Chemistry · 2022
Reported here: Cu(I)-TPT
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Cu(I)-TPT2022 · Constructing a Redox-Active Cu(I)-Pyridyltriazine Framework for Catalytic Photoreduction of Nitrobenzenes and Carboxylic Cyclization of Alkynol with CO2 | [Cu3(TPT)(CN)3.2CH3CN]; empirical crystal formula C25H18Cu3N11Cu(I) ions in 1D -Cu(I)-CN- chains; Cu(II) precursor reduced during synthesis · 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT); in situ generated cyanide groups | 2D · PristineMonoclinic C2/c redox-active MOF; 1D Cu(I)-CN chains connected by TPT into 2D sheets, stacked by pi-pi interactions into a porous 3D assembly. | p002 / 20658 · Results and Discussion - Synthesis and Crystal Structure · Figure 2 |