Electrochemistry Application — Constructing a Redox-Active Cu(I)-Pyridyltriazine Framework for Catalytic Photoreduction of Nitrobenzenes and Carboxylic Cyclization of Alkynol with CO2

3 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu(I)-TPT coated ITO photoelectrochemical electrode · Electrode

0.1 M Na2SO4 bath solution under dark and xenon lamp irradiation.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Relative EIS charge-transfer resistance	Cu(I)-TPT under visible light has a smaller Nyquist radius than TPT ligands	—	—	Qualitative Qualitative	p004 / 20660 · Characterizations · Figure 4e

Cu(I)-TPT coated ITO photoelectrochemical electrode · Electrode

Three-electrode system in 0.1 M Na2SO4 aqueous solution with Cu(I)-TPT-coated ITO working electrode, Pt counter, Ag/AgCl reference.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Flat-band potential	-0.69 V vs Ag/AgCl	-0.69 V vs Ag/AgCl	—	Text Exact Reported	p004 / 20660 · Characterizations · Figure 4c
Calculated HOMO potential	1.48 V vs NHE	1.48 V vs NHE	—	Text Exact Reported	p004 / 20660 · Characterizations · Figure 4c
Estimated LUMO potential	-0.49 V vs NHE	-0.49 V vs NHE	—	Text Exact Reported	p004 / 20660 · Characterizations · Figure 4c

Cu(I)-TPT coated ITO photoelectrochemical electrode · Electrode

Ag/AgCl counter/reference context reported; 0.1 M Na2SO4 electrolyte under xenon lamp irradiation with alternating dark/light cycles.

Atmosphere: N2 for electrochemical measurements
Geometry: Cu(I)-TPT/Nafion on ITO electrode
Context: pristine framework in electrode composite
Measurement source: S5 · 1.2.3 Photo-electrochemistry property test · Figure 4d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Relative transient photocurrent response	Cu(I)-TPT photocurrent density is higher than TPT and previously reported Cu(I)-BPY	—	—	Qualitative Qualitative	p004 / 20660 · Characterizations · Figure 4d