Electrical Transport — Constructing a Redox-Active Cu(I)-Pyridyltriazine Framework for Catalytic Photoreduction of Nitrobenzenes and Carboxylic Cyclization of Alkynol with CO2

Measurement evidence

Electrical Transport

Constructing a Redox-Active Cu(I)-Pyridyltriazine Framework for Catalytic Photoreduction of Nitrobenzenes and Carboxylic Cyclization of Alkynol with CO2 · Zhang T., Si C., Guo K. et al. · Inorganic Chemistry · 2022 · 20657-20665

1 measurement group · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Two-probe I-V conductivity with Keithley 2400 source meter / semiconductor analyser

Electrical conductivity

Cu(I)-TPT tablet for I-V conductivity · Pellet

Linear I-V sweep from -2 to 2 V under ambient conditions; dark, 300 W xenon irradiation, and xenon irradiation with ethanol sacrificial donor.

Temperature: ambient
Atmosphere: ambient
Geometry: Tablet, inner diameter 5 mm, thickness 0.6 mm, two Au wires (0.05 mm) attached with silver paste
Context: pristine framework pellet; ethanol-assisted condition includes guest/reductant environment
Measurement source: p007 / 20663 · Electronic Conductivity Measurement · Figure 4f and Figure S8

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Electronic conductivity under dark conditions	1.28 x 10^-11 S cm-1	1.28e-9 S m-1	—	Text Exact Reported	p003 / 20659 · Characterizations · Figure S8
Electronic conductivity under 300 W xenon irradiation	1.4 x 10^-11 S cm-1	1.4e-9 S m-1	—	Text Exact Reported	p003 / 20659 · Characterizations · Figure S8
Electronic conductivity under xenon irradiation with ethanolMarked as a best value within this paper	2 x 10^-7 S cm-1	0.00002 S m-1	—	Text Rounded Reported	p004 / 20660 · Characterizations · Figure 4f