Porosity — Constructing a Redox-Active Cu(I)-Pyridyltriazine Framework for Catalytic Photoreduction of Nitrobenzenes and Carboxylic Cyclization of Alkynol with CO2

Measurement evidence

Porosity

Constructing a Redox-Active Cu(I)-Pyridyltriazine Framework for Catalytic Photoreduction of Nitrobenzenes and Carboxylic Cyclization of Alkynol with CO2 · Zhang T., Si C., Guo K. et al. · Inorganic Chemistry · 2022 · 20657-20665

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CO2 temperature-programmed desorption

As-synthesised Cu(I)-TPT orange rhombus single crystals · Single Crystal

AutoChem II; sample activated at 200 C in helium for 30 min, saturated with CO2, purged with helium, then ramped to 700 C at 10 C min-1.

Atmosphere: He carrier/purge
Geometry: quartz reactor
Context: pristine framework
Measurement source: S5 · 1.2.2 CO2-TPD profiles · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Strong CO2 adsorption/desorption peak	460 C	733.15 K	—	Text Exact Reported	p003 / 20659 · Characterizations · Figure S6
Weak CO2 adsorption/desorption peak	334 C	607.15 K	—	Text Exact Reported	p003 / 20659 · Characterizations · Figure S6