Is iron unique in promoting electrical conductivity in MOFs?
Sun L., Hendon C.H., Park S.S. et al. · Chemical Science · 2017
Reported here: Fe2(DOBDC)(DMF)2
This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.
This metal-specific MOF-74/CPO-27 discovery family includes source-verified coordinated-solvent states, whose full formula and activation state remain attached to each record. Reviewed members are classified as 3D frameworks containing 1D channels; pore-direction and structural descriptions remain visible below. Guest-loaded, substituted-linker, mixed-metal and phase-unverified M₂(DOBDC) films remain separate materials.
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2 papers
Sun L., Hendon C.H., Park S.S. et al. · Chemical Science · 2017
Reported here: Fe2(DOBDC)(DMF)2
Sun L., Hendon C.H., Minier M.A. et al. · Journal of the American Chemical Society · 2015
Reported here: Fe2(DOBDC)
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Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Fe2(DOBDC)(DMF)22017 · Is iron unique in promoting electrical conductivity in MOFs? | Fe2(DOBDC)(DMF)2Fe2+ · DOBDC; DMF-coordinated | 3D · Pristinehoneycomb structure with 1D tubular pores | 4451 · Experimental results · Fig. 1 |
| Fe2(DOBDC)2015 · Million-fold electrical conductivity enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O) | Fe2(DOBDC)(DMF)2.x(DMF) and Fe2(DOBDC)(DMF)2 sample statesFe2+ chains, (-Fe-O-)inf secondary building units · DOBDC4- = 2,5-dihydroxybenzene-1,4-dicarboxylate | 3D · PristineMOF-74 analogue, structurally analogous to Mn2(DOBDC). | 6166 · main text · Figure 3 |