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1 papers
Darago L.E., Aubrey M.L., Yu C.J. et al. · Journal of the American Chemical Society · 2015
Reported here: (NBu4)2FeIII2(dhbq)3 (1)
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| (NBu4)2FeIII2(dhbq)3 (1)2015 · Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework | (NBu4)2FeIII2(dhbq)3; empirical formula C50H78Fe2N2O12High-spin FeIII centres. · Mixed-valent dhbq2-/dhbq3- linkers derived from 2,5-dihydroxybenzoquinone; charge balance implies 2:1 dhbq3-:dhbq2- ratio. | 3D · PristineCubic I-43d framework of two interpenetrated (10,3)-a nets of opposing chirality; tetrabutylammonium countercations fill pores. | 3 · Results and Discussion · Figure 2 |