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1 papers
Skorupskii G., Le K.N., Cordova D.L.M. et al. · Proceedings of the National Academy of Sciences of the United States of America · 2022
Reported here: Nd1.5HOTP; neodymium 2,3,6,7,10,11-hexaoxytriphenylene framework
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Nd1.5HOTP; neodymium 2,3,6,7,10,11-hexaoxytriphenylene framework2022 · Porous lanthanide metal–organic frameworks with metallic conductivity | Ln1.5(2,3,6,7,10,11-hexaoxytriphenylene), Ln = Nd; SI formula [Nd(OH)(OH2)]1.5HOTP . 2.9 H2O . 0.03 DMA . 0.1 Nd(NO3)3 . 0.06 MeOH . 0.16 CH3COOHNd3+ in lanthanide-oxygen coordination environment; DFT model uses one hydroxo and one aquo ligand per metal · 2,3,6,7,10,11-hexaoxytriphenylene (HOTP), from H6HOTP precursor | 2D · PristineStacked HOTP columns in a honeycomb-like framework; monoclinic C2/c at 375 K; incommensurate CDW modulation below about 370 K. | p002 · Results and Discussion · Fig. 1/Fig. 4 |