Metal-organic frameworks with fine-tuned interlayer spacing for microwave absorption
Zhang X., Tian X., Wu N. et al. · Science Advances · 2024
Reported here: Zn1Ni3-HHTP · Zn2Ni2-HHTP · Zn3Ni1-HHTP
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Zhang X., Tian X., Wu N. et al. · Science Advances · 2024
Reported here: Zn1Ni3-HHTP · Zn2Ni2-HHTP · Zn3Ni1-HHTP
Jiang H., Xian J., Hu R. et al. · Chemical Engineering Journal · 2023
Reported here: Bimetallic Zn,Ni-CAT conductive catecholate MOF · Symmetric all-solid-state supercapacitor using Zn,Ni-CAT electrodes
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Zn1Ni3-HHTP2024 · Metal-organic frameworks with fine-tuned interlayer spacing for microwave absorption | Zn/Ni-HHTP, Zn:Ni feed ratio 1:3mixed Zn2+/Ni2+ centres · HHTP | 2D · PristineBimetallic HHTP cMOF analogue used to demonstrate generality of interlayer tuning. | 22 · Fig. S15 caption · Fig. S15 |
| Zn2Ni2-HHTP2024 · Metal-organic frameworks with fine-tuned interlayer spacing for microwave absorption | Zn/Ni-HHTP, Zn:Ni feed ratio 1:1mixed Zn2+/Ni2+ centres · HHTP | 2D · PristineBimetallic HHTP cMOF analogue used to demonstrate generality of interlayer tuning. | 22 · Fig. S15 caption · Fig. S15 |
| Zn3Ni1-HHTP2024 · Metal-organic frameworks with fine-tuned interlayer spacing for microwave absorption | Zn/Ni-HHTP, Zn:Ni feed ratio 3:1mixed Zn2+/Ni2+ centres · HHTP | 2D · PristineBimetallic HHTP cMOF analogue used to demonstrate generality of interlayer tuning. | 22 · Fig. S15 caption · Fig. S15 |
| Bimetallic Zn,Ni-CAT conductive catecholate MOF2023 · Microwave discharge for rapid introduction of bimetallic-synergistic configuration to conductive catecholate toward long-term supercapacitor | Zn,Ni-CAT; Zn-doped/mixed-metal nickel catecholate frameworkNi and Zn metal nodes; partial Ni ions substituted by Zn ions, with Zn reported as Zn2+. · HHTP-derived catecholate linker. | 2D · PristineZn introduction preserves the Ni-CAT crystal structure while shifting the (100) diffraction peak to lower angle and increasing (100) lattice spacing to 1.85 nm. | 4 · 3.1. Synthesis and characterization · Figure 2 |
| Symmetric all-solid-state supercapacitor using Zn,Ni-CAT electrodes2023 · Microwave discharge for rapid introduction of bimetallic-synergistic configuration to conductive catecholate toward long-term supercapacitor | Zn,Ni-CAT electrode / PVA-KCl gel electrolyte / Zn,Ni-CAT electrodeNi and Zn nodes in the Zn,Ni-CAT electrode material. · HHTP-derived catecholate linker in Zn,Ni-CAT. | unknown · CompositeApplication device assembled from Zn,Ni-CAT electrodes and PVA/KCl gel electrolyte. | 8 · 3.4. Energy storage performance of Zn,Ni-CAT · Figure 7a |