Primary study2024
Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal-Organic Framework
Wang L., Daru A., Jangid B. et al. · Journal of the American Chemical Society · 2024
Reported here: Ni3(THT)2
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1 papers
Wang L., Daru A., Jangid B. et al. · Journal of the American Chemical Society · 2024
Reported here: Ni3(THT)2
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Ni3(THT)22024 · Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal-Organic Framework | Ni3(THT)2; Rietveld unit-cell formula C36H12Ni3S12; elemental analysis indicates residual DMF in powder batchessquare-planar Ni bis(dithiolene) units; Ni assigned primarily Ni(II) · THT, triphenylenehexathiolate / triphenylenehexathiol-derived dithiolene linker, formal oxidized THT3- linkers | 2D · PristineLayered 2D conductive MOF with hexagonal P6/mmm model, AA-like stacking, preserved crystallinity and hexagonal HRTEM lattice after transmetalation from Fe3(THT)2. | 2 · Results and Discussion - Synthesis, Structure, and Component Redox States · Figure 1D; Figure 2; Table S3 |