Thermoelectric — Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal-Organic Framework

Measurement evidence

Thermoelectric

Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal-Organic Framework · Wang L., Daru A., Jangid B. et al. · Journal of the American Chemical Society · 2024 · 12063-12073

1 measurement group · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Room-temperature four-probe conductivity and Seebeck coefficient

Electrical conductivity Seebeck and thermopower measurements

Ni3(THT)2 pressed pellet for four-probe and Seebeck measurements · Pellet

custom probe station in argon glovebox; forward and reverse Seebeck scans; geometry correction for conductivity and Seebeck

Temperature: 300
Atmosphere: argon glovebox
Geometry: 8 mm pressed pellet, 200 um probe spacing, Au contacts
Context: pristine pressed pellet
Measurement source: 4 · Bulk Electronic Structure · Table S4; Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermoelectric carrier sign	negative Seebeck; n-type thermoelectric behavior	—	—	Text Qualitative	4 · Bulk Electronic Structure
Geometry-adjusted Seebeck coefficient batch 1	-7.9 uV/K	—	—	SI Table Exact Reported	13 · Characterization Data · Table S4
Geometry-adjusted Seebeck coefficient batch 2	-29.8 uV/K	—	—	SI Table Exact Reported	13 · Characterization Data · Table S4
Geometry-adjusted Seebeck coefficient batch 3	-29.6 uV/K	—	—	SI Table Exact Reported	13 · Characterization Data · Table S4
Room-temperature Seebeck coefficient Fe3(THT)2	-20.7 uV K^-1	—	—	Text Rounded Reported	4 · Bulk Electronic Structure
Room-temperature Seebeck coefficient Ni3(THT)2Marked as a best value within this paper	-22.1 uV K^-1	—	—	Text Rounded Reported	4 · Bulk Electronic Structure · Table S4
Average bulk electrical conductivity Ni3(THT)2Marked as a best value within this paper	0.32(9) S cm^-1	—	(9)	Text Rounded Reported	4 · Bulk Electronic Structure · Table S4
Four-probe conductivity batch 1	0.18 S/cm	—	—	SI Table Exact Reported	13 · Characterization Data · Table S4
Four-probe conductivity batch 2	0.4 S/cm	—	—	SI Table Exact Reported	13 · Characterization Data · Table S4
Four-probe conductivity batch 3	0.39 S/cm	—	—	SI Table Exact Reported	13 · Characterization Data · Table S4
Bulk electrical conductivity Fe3(THT)2 comparison	7.8(3) x 10^-2 S cm^-1	—	(3)	Text Rounded Reported	4 · Bulk Electronic Structure