Other — Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal-Organic Framework

Measurement evidence

Other

Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal-Organic Framework · Wang L., Daru A., Jangid B. et al. · Journal of the American Chemical Society · 2024 · 12063-12073

2 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Elemental analysis

Bulk elemental and compositional analysis

Ni3(THT)2 black powder · Powder

CHN elemental analysis of two Ni3(THT)2 batches

Geometry: powder
Context: pristine Ni3(THT)2 with residual DMF assignment
Measurement source: 7 · Characterization Data · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Elemental analysis C% batch 1	43.32	—	—	SI Table Exact Reported	7 · Characterization Data · Table S2
Assigned DMF content batch 1	(C3H7NO)2.0	—	—	SI Table Exact Reported	7 · Characterization Data · Table S2
Elemental analysis H% batch 1	2.81	—	—	SI Table Exact Reported	7 · Characterization Data · Table S2
Elemental analysis N% batch 1	2.44	—	—	SI Table Exact Reported	7 · Characterization Data · Table S2
Elemental analysis C% batch 2	43.64	—	—	SI Table Exact Reported	7 · Characterization Data · Table S2
Assigned DMF content batch 2	(C3H7NO)2.8	—	—	SI Table Exact Reported	7 · Characterization Data · Table S2
Elemental analysis H% batch 2	2.64	—	—	SI Table Exact Reported	7 · Characterization Data · Table S2
Elemental analysis N% batch 2	3.35	—	—	SI Table Exact Reported	7 · Characterization Data · Table S2

SQUID magnetic susceptibility and ZFC/FC magnetisation

Magnetometry and magnetic susceptibility

Ni3(THT)2 black powder · Powder

Quantum Design MPMS3; powder suspended in eicosane matrix in polycarbonate capsule; chiT from 2-300 K and 50-335 K; ZFC/FC under 1000 Oe

Temperature: 2-335
Atmosphere: N2-filled glovebox sample protection before measurement
Geometry: bulk powder in eicosane/capsule
Context: pristine Ni3(THT)2
Measurement source: 4 · Bulk Electronic Structure · Figures S15-S16

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Curie-Weiss theta for Fe3(THT)2 comparison	-123.7 K	—	—	Text Rounded Reported	4 · Bulk Electronic Structure
Curie-Weiss theta for Ni3(THT)2	-8.9 K	—	—	Text Rounded Reported	4 · Bulk Electronic Structure · Figure S15c
ZFC/FC divergence	no divergence	—	—	Text Qualitative	4 · Bulk Electronic Structure · Figure S16