Electrochemistry Application — Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal-Organic Framework

3 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Fe3(THT)2 coated conductive-paper electrode · Electrode

0.2 M LiPF6/DMF electrolyte; Fe3(THT)2 coated conductive paper working electrode

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Fe3(THT)2 electrochemical decomposition	decomposition after one cycle, especially anodically above -0.5 V	—	—	Text Qualitative	6 · Electrochemical Properties · Figure S24
Fe3(THT)2 irreversible/quasi-reversible CV window	-0.8 to 0.8 V vs Fc/Fc+	—	—	Text Rounded Reported	6 · Electrochemical Properties · Figure S24

Ni3(THT)2/Super P/PVDF carbon-paper electrode · Electrode

0.2 M LiPF6/DMF electrolyte; scan rates 1-15 mV s^-1; Pt counter, Ag pseudoreference, Fc/Fc+ calibration

Atmosphere: N2 glovebox
Geometry: Ni3(THT)2/Super P/PVDF on conductive carbon paper working electrode
Context: composite electrode containing pristine Ni3(THT)2 active material
Measurement source: 6 · Electrochemical Properties · Figure 7; Figure S25

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DMF b-value anodic peak	b = 0.90	—	—	Figure Axis Approximate	7 · Electrochemical Properties · Figure 7C
DMF b-value cathodic peak	b = 0.91	—	—	Figure Axis Approximate	7 · Electrochemical Properties · Figure 7C
Specific capacitance in LiPF6/DMF at 15 mV/s	~54.5 F/g	—	—	Figure Axis Approximate	7 · Electrochemical Properties · Figure 7D
Specific capacitance in LiPF6/DMF at 1 mV/sMarked as a best value within this paper	67 F/g	—	—	Text Rounded Reported	6 · Electrochemical Properties · Figure 7D
Ni3(THT)2 cycling stability in CV	no decomposition during cycling	—	—	Text Qualitative	6 · Electrochemical Properties · Figure 7
Ni3(THT)2 broad symmetric CV waveform window in DMF	-0.7 to -1.4 V vs Fc/Fc+	—	—	Text Rounded Reported	6 · Electrochemical Properties · Figure 7A
Active material mass per electrochemical substrate	~1-2 mg per sample	—	—	Text Approximate	8 · Experimental Section - Electrode Fabrication

Ni3(THT)2/Super P/PVDF carbon-paper electrode · Electrode

0.2 M LiPF6/MeCN electrolyte; scan rates 1-15 mV s^-1

Atmosphere: N2 glovebox
Geometry: Ni3(THT)2/Super P/PVDF on conductive carbon paper working electrode
Context: composite electrode containing pristine Ni3(THT)2 active material
Measurement source: 27 · Characterization Data · Figure S26

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MeCN b-value anodic peak	b = 0.98	—	—	Figure Axis Approximate	27 · Characterization Data · Figure S26C
MeCN b-value cathodic peak	b = 0.89	—	—	Figure Axis Approximate	27 · Characterization Data · Figure S26C
Specific capacitance in LiPF6/MeCN at 15 mV/s	~37 F/g	—	—	Figure Axis Approximate	27 · Characterization Data · Figure S26D
Specific capacitance in LiPF6/MeCN at 1 mV/sMarked as a best value within this paper	47 F/g	—	—	Text Rounded Reported	6 · Electrochemical Properties · Figure S26d