Primary study2016
Electrical conductivity and electroluminescence of a new anthracene-based metal-organic framework with π-conjugated zigzag chains
Chen D., Xing H., Su Z. et al. · Chemical Communications · 2016
Reported here: NNU-27
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1 papers
Chen D., Xing H., Su Z. et al. · Chemical Communications · 2016
Reported here: NNU-27
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| NNU-272016 · Electrical conductivity and electroluminescence of a new anthracene-based metal-organic framework with π-conjugated zigzag chains | [ZnNa2(L)2(DEF)2].DEF; CIF formula sum C74 H54 N2 Na2 O10 ZnInfinite bimetal Na+/Zn2+ chain with Na+/Zn2+ molar ratio 2:1; Zn2+ tetrahedral carboxylate coordination and Na+ distorted octahedral carboxylate/DEF coordination. · L2- from H2L, 4,4'-(anthracene-9,10-diylbis(ethyne-2,1-diyl))-dibenzoic acid; anthracene-based dicarboxylate linker with long-range pi-stacked zigzag arrangement. | 3D · PristineTetragonal P42/nbc three-dimensional microporous framework; anthracene ligands stack in zigzag chains along the crystallographic c-axis and form double-wall carbon-nanotube-mimicking channels. | p002-p003 · Main text · Figure 1 |