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1 papers
Tkachov R., Stepien L., Grafe R. et al. · Polymer Chemistry · 2018
Reported here: poly[Ni-tto] nickel polytetrathiooxalate coordination polymer
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| poly[Ni-tto] nickel polytetrathiooxalate coordination polymer2018 · Polyethenetetrathiolate or polytetrathiooxalate? Improved synthesis, a comparative analysis of a prominent thermoelectric polymer and implications to the charge transport mechanism | poly[Ni-tto]; ideal repeat approximated as nickel tetrathiooxalate, experimentally P3 contains low K attributed to chain endsNi2+ centres coordinated by tetrathiooxalate sulphur donor atoms. · tetrathiooxalate (tto2-) from potassium tetrathiooxalate K2tto | 1D · PristineCoordination polymer chains; predicted P3 unit cell orthorhombic Pna21 with close Ni-Ni contacts and stable pi-stacked/herringbone packing. | 1 · Abstract |