Electrical Transport — Electrical conductivity through π–π stacking in a two-dimensional porous gallium catecholate metal–organic framework

Measurement evidence

Electrical Transport

Electrical conductivity through π–π stacking in a two-dimensional porous gallium catecholate metal–organic framework · Skorupskii G., Chanteux G., Le K.N. et al. · Annals of the New York Academy of Sciences · 2022 · 226-230

3 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Pressed-pellet current-voltage measurement

Pressed pellet of Ga9(HOTP)4 · Pellet

Sample I-V curve for a pressed pellet; linear fit used to demonstrate Ohmic behaviour.

Temperature
room temperature
Geometry
Pressed pellet
Context
Pristine Ga9(HOTP)4 pellet
Measurement source
main p.229 · Figure caption · Figure 4C
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Approximate current at +0.1 Vapproximately 3.9 microA at +0.1 V0.0000039 Avisual estimate from Figure 4C axisFigure Axis
Approximate
main p.229 · Figure panel · Figure 4C
I-V linear-fit R2R2 = 0.9990.999Caption
Exact Reported
main p.229 · Figure caption · Figure 4C

Two-probe pressed-pellet resistivity/conductivity measurement

Pressed pellet of Ga9(HOTP)4 · Pellet

Room-temperature conductivity measured over three independent batches; each point in Figure 4A represents a separate device.

Temperature
room temperature
Geometry
Pressed pellet, two-probe
Context
Pristine Ga9(HOTP)4 pellet
Measurement source
main p.229 · Results and discussion · Figure 4A
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Maximum plotted room-temperature conductivityapproximately 8.6 mS/cm0.0086 S/cmvisual estimate from y-axisFigure Axis
Approximate
main p.229 · Figure panel · Figure 4A
Median room-temperature electrical conductivityMarked as a best value within this paper3.3 mS/cm0.0033 S/cmCaption
Exact Reported
main p.229 · Figure caption · Figure 4A
Minimum plotted room-temperature conductivityapproximately 0.6 mS/cm0.0006 S/cmvisual estimate from y-axisFigure Axis
Approximate
main p.229 · Figure panel · Figure 4A
Lower quartile plotted conductivityapproximately 2.2 mS/cm0.0022 S/cmvisual estimate from box plotFigure Axis
Approximate
main p.229 · Figure panel · Figure 4A
Upper quartile plotted conductivityapproximately 4.3 mS/cm0.0043 S/cmvisual estimate from box plotFigure Axis
Approximate
main p.229 · Figure panel · Figure 4A

Variable-temperature electrical conductivity fit to 3D Mott variable-range hopping

Pressed pellet of Ga9(HOTP)4 · Pellet

Temperature-dependent conductivity of pressed pellets fit between 100 and 290 K using a three-dimensional Mott VRH law.

Temperature
100-290
Geometry
Pressed pellet
Context
Pristine Ga9(HOTP)4 pellet
Measurement source
main p.227 · Results and discussion · Figure 4B
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Best-fit transport modelThree-dimensional Mott variable-range hoppingText
Qualitative
main p.227 · Results and discussion · Figure 4B
Lower temperature bound for VRH fit100 K100 KText
Exact Reported
main p.227 · Results and discussion · Figure 4B
Upper temperature bound for VRH fit290 K290 KText
Exact Reported
main p.227 · Results and discussion · Figure 4B