Electrical Transport — Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction

6 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

c-HBC-12O-Cu pellet · Pellet

Bulk polycrystalline pellet; Keithley 4200-SCS; room-temperature conductivity; temperature-dependent measurements from 303 to 348 K also reported.

Temperature: room temperature
Geometry: pellet, diameter 3 mm, thickness 1.054 mm, two-probe
Context: pristine framework pellet
Measurement source: S23 / p023 · Electrical Conductivity · Table S3; Figure S28; Figure S29

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivityMarked as a best value within this paper	3.31 S m-1	0.0331 S cm-1	—	SI Table Exact Reported	S23 / p023 · Electrical Conductivity · Table S3
Temperature-dependent conductivity trend	Conductivity increases almost linearly with increasing temperature from 303 to 348 K	—	—	Text Qualitative	p006 / article p8984 · Results and Discussion · Figure S29

c-HBC-12O-Cu film for OPTP · Thin Film

800 nm femtosecond laser pulses; pump fluence about 1.3 mJ cm-2; dry N2; frequency spectra recorded about 0.5 ps after maximum photoconductivity.

Atmosphere: dry N2
Geometry: thin-film approximation
Context: pristine framework film
Measurement source: p006-p007 / article p8984-p8985 · Results and Discussion · Figure 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DC charge-carrier mobility from THz/Drude-Smith analysisMarked as a best value within this paper	64 cm2 V-1 s-1	—	—	Text Exact Reported	p007 / article p8985 · Results and Discussion · Figure 5; Table S6
Relative photoconductivityMarked as a best value within this paper	about 5 times higher than the other two MOFs	—	~	Text Approximate	p007 / article p8985 · Results and Discussion · Figure 5b
Drude-Smith charge scattering time tauMarked as a best value within this paper	89 +/- 3 fs	—	+/- 3 fs	Text Exact Reported	p007 / article p8985 · Results and Discussion · Figure 5e

c-HBC-6O-Cu pellet · Pellet

Bulk polycrystalline pellet; Keithley 4200-SCS; room-temperature conductivity; temperature-dependent measurements from 303 to 348 K also reported.

Temperature: room temperature
Geometry: pellet, diameter 3 mm, thickness 1.322 mm, two-probe
Context: pristine framework pellet
Measurement source: S23 / p023 · Electrical Conductivity · Table S3; Figure S28; Figure S29

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity	1.95 x 10-2 S m-1	0.000195 S cm-1	—	SI Table Exact Reported	S23 / p023 · Electrical Conductivity · Table S3

c-HBC-6O-Cu film for OPTP · Thin Film

800 nm femtosecond laser pulses; pump fluence about 1.3 mJ cm-2; dry N2; frequency spectra recorded about 0.5 ps after maximum photoconductivity.

Atmosphere: dry N2
Geometry: thin-film approximation
Context: pristine framework film
Measurement source: S4 / p004 · Time- and frequency-resolved THz photoconductivity measurements · Figure 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DC charge-carrier mobility from THz/Drude-Smith analysis	48 cm2 V-1 s-1	—	—	Text Exact Reported	p007 / article p8985 · Results and Discussion · Figure 5; Table S6
Drude-Smith charge scattering time tau	63 +/- 4 fs	—	+/- 4 fs	Text Exact Reported	p007 / article p8985 · Results and Discussion · Figure 5c

c-HBC-8O-Cu pellet · Pellet

Bulk polycrystalline pellet; Keithley 4200-SCS; room-temperature conductivity; temperature-dependent measurements from 303 to 348 K also reported.

Temperature: room temperature
Geometry: pellet, diameter 3 mm, thickness 1.432 mm, two-probe
Context: pristine framework pellet
Measurement source: S23 / p023 · Electrical Conductivity · Table S3; Figure S28; Figure S29

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity	1.14 x 10-1 S m-1	0.00114 S cm-1	—	SI Table Exact Reported	S23 / p023 · Electrical Conductivity · Table S3

c-HBC-8O-Cu film for OPTP · Thin Film

800 nm femtosecond laser pulses; pump fluence about 1.3 mJ cm-2; dry N2; frequency spectra recorded about 0.5 ps after maximum photoconductivity.

Atmosphere: dry N2
Geometry: thin-film approximation
Context: pristine framework film
Measurement source: S4 / p004 · Time- and frequency-resolved THz photoconductivity measurements · Figure 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DC charge-carrier mobility from THz/Drude-Smith analysis	38 cm2 V-1 s-1	—	—	Text Exact Reported	p007 / article p8985 · Results and Discussion · Figure 5; Table S6
Drude-Smith charge scattering time tau	78 +/- 2 fs	—	+/- 2 fs	Text Exact Reported	p007 / article p8985 · Results and Discussion · Figure 5d