Synthesis · Conjugated Nonplanar Copper-Catecholate Conductive Metal-Organic Frameworks via Contorted Hexabenzocoronene Ligands for Electrical Conduction

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

S9 / p009 · Synthesis of c-HBC-12O-Cu · Scheme S8

Metal precursorsCu(NO3)2.3H2O (38.7 mg, 0.16 mmol) in H2O (2.3 mL)

Linker precursorsc-HBC-12OH (31.7 mg, 0.04 mmol) in DMF (0.2 mL)

SolventsH2O; N,N-dimethylformamide (DMF)

Atmospherenot specified

Temperature85

Time72

Work-upSonicated 10 min; cooled to room temperature; precipitate collected by centrifugation and washed with water, DMF and acetone.

ActivationDried under vacuum for 24 h at room temperature.

Scalability contextPreparative scale reported in tens of milligrams with 96% yield.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(NO3)2.3H2O	38.7 mg, 0.16 mmol	S9 / p009 · Synthesis of c-HBC-12O-Cu · Scheme S8
Linker	c-HBC-12OH	31.7 mg, 0.04 mmol	S9 / p009 · Synthesis of c-HBC-12O-Cu · Scheme S8
Solvent	H2O	2.3 mL	S9 / p009 · Synthesis of c-HBC-12O-Cu · Scheme S8
Solvent	DMF	0.2 mL	S9 / p009 · Synthesis of c-HBC-12O-Cu · Scheme S8

Complete recipeSource: Both

S8 / p008 · Synthesis of c-HBC-6O-Cu · Scheme S6

Metal precursorsCu(NO3)2.3H2O (9.6 mg, 0.04 mmol) in H2O (2.0 mL)

Linker precursorsc-HBC-6OH (7.0 mg, 0.01 mmol) in DMAc (0.5 mL)

SolventsH2O; N,N-dimethylacetamide (DMAc)

Atmospherenot specified

Temperature85

Time72

Work-upSonicated 10 min; cooled to room temperature; precipitate collected by centrifugation and washed with water, DMF and acetone.

ActivationDried under vacuum for 24 h at room temperature.

Scalability contextPreparative scale reported in milligrams with 78% yield.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(NO3)2.3H2O	9.6 mg, 0.04 mmol	S8 / p008 · Synthesis of c-HBC-6O-Cu · Scheme S6
Linker	c-HBC-6OH	7.0 mg, 0.01 mmol	S8 / p008 · Synthesis of c-HBC-6O-Cu · Scheme S6
Solvent	H2O	2.0 mL	S8 / p008 · Synthesis of c-HBC-6O-Cu · Scheme S6
Solvent	DMAc	0.5 mL	S8 / p008 · Synthesis of c-HBC-6O-Cu · Scheme S6

Complete recipeSource: Both

S9 / p009 · Synthesis of c-HBC-8O-Cu · Scheme S7

Metal precursorsCu(NO3)2.3H2O (48.3 mg, 0.2 mmol) in H2O (4.6 mL)

Linker precursorsc-HBC-8OH (36.4 mg, 0.05 mmol) in DMF (0.4 mL)

SolventsH2O; N,N-dimethylformamide (DMF)

Atmospherenot specified

Temperature85

Time72

Work-upSonicated 10 min; cooled to room temperature; precipitate collected by centrifugation and washed with water, DMF and acetone.

ActivationDried under vacuum for 24 h at room temperature.

Scalability contextPreparative scale reported in tens of milligrams with 92% yield.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(NO3)2.3H2O	48.3 mg, 0.2 mmol	S9 / p009 · Synthesis of c-HBC-8O-Cu · Scheme S7
Linker	c-HBC-8OH	36.4 mg, 0.05 mmol	S9 / p009 · Synthesis of c-HBC-8O-Cu · Scheme S7
Solvent	H2O	4.6 mL	S9 / p009 · Synthesis of c-HBC-8O-Cu · Scheme S7
Solvent	DMF	0.4 mL	S9 / p009 · Synthesis of c-HBC-8O-Cu · Scheme S7