Electrical Transport — Millimeter-scale semiconductive metal-organic framework single crystal for X-ray imaging

Measurement evidence

Electrical Transport

Millimeter-scale semiconductive metal-organic framework single crystal for X-ray imaging · Cheng L., Liang C., Li B. et al. · Cell Reports Physical Science · 2022 · 101004

3 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Bias-dependent photoconductivity fitted with modified Hecht equation

SCU-15 SC device · Single Crystal

SCU-15 SC and SCU-15 PP bias-dependent photocurrent curves fitted to obtain carrier mobility-lifetime product and diffusion length.

Geometry
Ag-contacted single-crystal and pellet X-ray detector devices
Context
pristine SCU-15 single-crystal device and pristine SCU-15 pellet device
Measurement source
main p.6 and p.10 · Comparison of optoelectronic properties; Charge mobility and mt calculations · Figures 4E-4F
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
SCU-15 SC mu_tau improvement over PPnearly five times higher than pelleted polycrystalline deviceText
Approximate
main p.6 · Comparison of optoelectronic properties · Figures 4E-4F
SCU-15 PP carrier diffusion length34.2 umText
Exact Reported
main p.6 · Comparison of optoelectronic properties · Figure 4F
SCU-15 PP charge-carrier mobility-lifetime product4.78 x 10^-4 cm2 V^-1Text
Exact Reported
main p.6 · Comparison of optoelectronic properties · Figure 4F; Table S4
SCU-15 SC carrier diffusion lengthMarked as a best value within this paper74.8 umText
Exact Reported
main p.6 · Comparison of optoelectronic properties · Figure 4E
SCU-15 SC charge-carrier mobility-lifetime productMarked as a best value within this paper2.18 x 10^-3 cm2 V^-1Text
Exact Reported
main p.6 · Comparison of optoelectronic properties · Figure 4E; Table S4

Dark current-voltage measurement

SCU-15 SC device · Single Crystal

Dark I-V curves from -10 V to 10 V with 0.2 V sweeping step; SCU-15 SC and SCU-15 PP compared.

Geometry
Ag/SCU-15/Ag detector devices
Context
pristine SCU-15 single crystal and pristine SCU-15 pellet devices
Measurement source
SI p.6 · Supplemental Items · Figure S13
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
SCU-15 PP resistivity4.79 x 10^12 Ohm cmText
Exact Reported
main p.5 · Comparison of optoelectronic properties · Figure S13; Table S4
SCU-15 SC bulk resistivity6.18 x 10^11 Ohm cmText
Exact Reported
main p.5 · Comparison of optoelectronic properties · Figure S13; Table S4

Current-voltage measurement under X-ray irradiation

SCU-15 SC device · Single Crystal

SCU-15 SC I-V curves from -4 to +4 V under X-ray irradiation with different tube voltages and currents; tungsten anode RAD SOURCE RS 2000X.

Geometry
vertical photoconductor in cathode irradiation configuration; Ag/SCU-15 single crystal/Ag
Context
pristine SCU-15 single-crystal device
Measurement source
main p.5 and p.10 · Comparison of optoelectronic properties; X-ray detection measurement · Figure 4D
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
SCU-15 SC I-V behaviour under X-rayLinear dependence; Ohmic contact between single crystal and electrodesText
Qualitative
main p.5 · Comparison of optoelectronic properties · Figure 4D
SCU-15 SC I-V sweep range under X-ray-4 to +4 VText
Exact Reported
main p.5 · Comparison of optoelectronic properties · Figure 4D