Sensing Application — Millimeter-scale semiconductive metal-organic framework single crystal for X-ray imaging

Measurement evidence

Sensing Application

Millimeter-scale semiconductive metal-organic framework single crystal for X-ray imaging · Cheng L., Liang C., Li B. et al. · Cell Reports Physical Science · 2022 · 101004

5 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

2 x 3 pixelated X-ray imaging demonstration

SCU-15 2 x 3 single-crystal array detector · Electrode

L-shaped lead plate on detector; 120 keV peak X-ray energy; photocurrent recorded at 1 V bias and converted to colour gradient.

Geometry
2 x 3 SCU-15 single-crystal pixelated array detector
Context
pristine SCU-15 single-crystal array detector
Measurement source
main p.8 · X-ray detection performance · Figure 5E; Figure S21
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Array X-ray imaging resultObvious L-shaped imaging result obtainedText
Qualitative
main p.8 · X-ray detection performance · Figure 5E
Array imaging X-ray peak energy120 keVText
Exact Reported
main p.8 · X-ray detection performance · Figure 5E; Figure S21
SCU-15 array pixel 1 photocurrent5.25 x 10^-11 AVisual Estimate
Rounded Reported
SI p.9 · Supplemental Items · Figure S21
SCU-15 array pixel 2 photocurrent5.64 x 10^-11 AVisual Estimate
Rounded Reported
SI p.9 · Supplemental Items · Figure S21
SCU-15 array pixel 3 photocurrent4.60 x 10^-11 AVisual Estimate
Rounded Reported
SI p.9 · Supplemental Items · Figure S21
SCU-15 array pixel 4 photocurrent2.78 x 10^-10 AVisual Estimate
Rounded Reported
SI p.9 · Supplemental Items · Figure S21
SCU-15 array pixel 5 photocurrent2.36 x 10^-10 AVisual Estimate
Rounded Reported
SI p.9 · Supplemental Items · Figure S21
SCU-15 array pixel 6 photocurrent5.81 x 10^-11 AVisual Estimate
Rounded Reported
SI p.9 · Supplemental Items · Figure S21

Signal-to-noise ratio versus low X-ray dose rate

SCU-15 SC device · Single Crystal

Detection limit defined as dose rate at SNR = 3 under a given electric field; SCU-15 SC and PP compared.

Geometry
Ag-contacted single-crystal and pellet X-ray detector devices
Context
pristine SCU-15 single-crystal device and pristine SCU-15 pellet device
Measurement source
main p.7 and p.10 · X-ray detection performance; Detection limit calculation · Figure 5D; Figure S17; Table S4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
SCU-15 PP X-ray detection limit104.26 uGyair s^-1Text
Exact Reported
main p.7 · X-ray detection performance · Figure S17; Table S4
SCU-15 SC X-ray detection limitMarked as a best value within this paper33.96 uGyair s^-1Text
Exact Reported
main p.7 · X-ray detection performance · Figure 5D; Table S4

Time-dependent X-ray photocurrent response

SCU-15 SC device · Single Crystal

SCU-15 SC photocurrent response under dose rates from 2.75 to 0.53 mGyair/s; additional bias test from 1 to 15 V at 17.52 mGyair/s.

Geometry
Ag/SCU-15 single crystal/Ag detector under X-ray irradiation
Context
pristine SCU-15 single-crystal device
Measurement source
main p.7 · X-ray detection performance · Figure 5A; Figure S16
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Dose rate for bias-dependent X-ray response17.52 mGyair/sText
Exact Reported
main p.7 · X-ray detection performance · Figure S16
Dose-rate range for SCU-15 SC time response2.75 to 0.53 mGyair/sCaption
Range
main p.7 · Figure 5 caption · Figure 5A

Current-density versus X-ray dose-rate sensitivity measurement

SCU-15 SC device · Single Crystal

Bias voltage 1 V; SCU-15 SC and SCU-15 PP compared by current density versus X-ray dose rate.

Geometry
Ag-contacted single-crystal and pellet X-ray detector devices
Context
pristine SCU-15 single-crystal device and pristine SCU-15 pellet device
Measurement source
main p.7 and p.10 · X-ray detection performance; Sensitivity calculation · Figure 5C
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
SCU-15 PP X-ray detection sensitivity0.40 uC Gyair^-1 cm^-2 at 1 V biasText
Exact Reported
main p.7 · X-ray detection performance · Figure 5C; Table S4
SCU-15 SC X-ray detection sensitivityMarked as a best value within this paper3.51 uC Gyair^-1 cm^-2 at 1 V biasText
Exact Reported
main p.7 · X-ray detection performance · Figure 5C; Table S4

Operational X-ray stability and post-irradiation PXRD

SCU-15 SC device · Single Crystal

SCU-15 SC tested before and after 126.1 Gyair hard X-ray irradiation at 17.52 mGyair/s for 120 min.

Geometry
Ag/SCU-15 single crystal/Ag detector
Context
pristine SCU-15 single-crystal device
Measurement source
main p.7-p.8 · X-ray detection performance · Figures S18-S19
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Post-irradiation response and crystallinityPhotoelectric response and crystallinity almost unchanged after irradiationText
Qualitative
main p.7-p.8 · X-ray detection performance · Figures S18-S19
Hard X-ray irradiation dose for stability test126.1 GyairText
Exact Reported
main p.7-p.8 · X-ray detection performance · Figures S18-S19