Porosity — Conductive Metal-Organic Frameworks for Amperometric Sensing of Paracetamol

Measurement evidence

Porosity

Conductive Metal-Organic Frameworks for Amperometric Sensing of Paracetamol · Wang J., Liu S., Luo J. et al. · Frontiers in Chemistry · 2020 · 594093

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Rendered CPK structural size comparison

As-synthesised NiCu-CAT nanocrystals · Powder

Supplementary Figure 7 shows paracetamol dimensions and NiCu-CAT channel relationship along [001] and [110].

Geometry
Modelled framework/analyte comparison.
Context
Pristine mixed-metal NiCu-CAT framework model compared with paracetamol.
Measurement source
SI p.4 · Supplementary Figures · Supplementary Figure 7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NiCu-CAT labelled pore/channel dimension in SI figure12.896 AngstromVisual Estimate
Approximate
SI p.4 · Supplementary Figures · Supplementary Figure 7
Paracetamol labelled long molecular dimension in SI figure8.212 AngstromVisual Estimate
Approximate
SI p.4 · Supplementary Figures · Supplementary Figure 7
Paracetamol labelled short molecular dimension in SI figure3.700 AngstromVisual Estimate
Approximate
SI p.4 · Supplementary Figures · Supplementary Figure 7

Structural modelling / CPK pore-size comparison

As-synthesised NiCu-CAT nanocrystals · Powder

Materials Studio 8.0 model based on the CIF of Ni-CAT; Supplementary Figure 7 compares paracetamol size with the Ni/Cu-CAT channel.

Geometry
Modelled framework channel
Context
Pristine mixed-metal NiCu-CAT framework.
Measurement source
main p.3 and p.7 · Instrumentation; Analytical Performance Characteristics · Supplementary Figure 7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Paracetamol molecule dimensions used for host-guest comparison8.3 Angstrom x 3.7 AngstromText
Rounded Reported
main p.7 · Analytical Performance Characteristics · Supplementary Figure 7
Ni/Cu-CAT channel pore size13 AngstromText
Rounded Reported
main p.7 · Analytical Performance Characteristics · Supplementary Figure 7