Diffraction Structure — Tunneling Electrical Connection to the Interior of Metal-Organic Frameworks

Measurement evidence

Diffraction Structure

Tunneling Electrical Connection to the Interior of Metal-Organic Frameworks · Han S., Warren S.C., Yoon S.M. et al. · Journal of the American Chemical Society · 2015 · 8169-8175

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Powder X-ray diffraction (PXRD)

X-ray diffraction and scattering

AgNC@Rb-CD-MOF from 10 mM AgNO3 · Single Crystal

Blank and AgNC@Rb-CD-MOF after infiltration and after white-light irradiation at 595 mW/cm2 for 24 h

Geometry: powder/crystal diffraction
Context: pristine vs AgNC-loaded series
Measurement source: 4-5 · Section 3 · Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FCC Ag (111) PXRD peak	38.5 degrees 2theta for (111) Bragg reflection	—	—	Caption Rounded Reported	S5 · Section 3 · Figure S1
FCC Ag (200) PXRD peak	44 degrees 2theta for (200) Bragg reflection	—	—	Caption Rounded Reported	S5 · Section 3 · Figure S1
Rb-CD-MOF PXRD after AgNC infiltration	no significant changes after AgNC infiltration and/or 595 mW/cm2 white-light irradiation for 24 h	—	—	Caption Qualitative	S4 · Section 3 · Figure S1

crystal structure description / unit-cell schematic

Blank Rb-CD-MOF single crystals · Single Crystal

Rb-CD-MOF cavities and channels described from prior structure and Figure 1 schematic

Geometry: not applicable
Context: pristine framework
Measurement source: 2 · Results and Discussion · Figure 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Rb-CD-MOF cavity diameter	~1.7 nm cavity	—	—	Caption Approximate	2 · Results and Discussion · Figure 1
Rb-CD-MOF channel width	~0.8 nm wide channels	—	—	Caption Approximate	2 · Results and Discussion · Figure 1