Electrical Transport — Tunneling Electrical Connection to the Interior of Metal-Organic Frameworks

8 measurement groups · 28 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

conductivity cycling under argon flow

Electrical conductivity

AgNC@Rb-CD-MOF from 10 mM AgNO3 · Single Crystal

Alternating irradiation cycles; 1.48 W/cm2; Ar pressure ~2 atm; wavelength cut-on filter experiment in Figure S5b

Temperature: 334 K for S5a illuminated AgNC cycles; 304-318 K for wavelength-filtered S5b labels
Atmosphere: argon flow, pressure ~2 atm
Geometry: two-probe crystal device
Context: AgNC-loaded versus blank Rb-CD-MOF
Measurement source: 10 · Section 5 · Figure S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
AgNC@Rb-CD-MOF argon-flow dark plateau	~2.0 x 10^-10 S/cm between irradiation pulses	—	—	Figure Axis Approximate	S10 · Section 5 · Figure S5a
AgNC@Rb-CD-MOF argon-flow illuminated plateau	~8.8 x 10^-10 S/cm under 1.48 W/cm2 at 334 K	—	—	Figure Axis Approximate	S10 · Section 5 · Figure S5a
Highest wavelength-filter response in Figure S5b	~4.5 x 10^-10 S/cm near 500 nm cut-on, 318 K	—	—	Figure Axis Approximate	S10 · Section 5 · Figure S5b
Blank Rb-CD-MOF argon-flow conductivity	~4.5-6.0 x 10^-12 S/cm	—	—	Figure Axis Range	S10 · Section 5 · Figure S5a

extended cyclic photoconductivity under high-intensity light

AgNC@Rb-CD-MOF from 10 mM AgNO3 · Single Crystal

1.48 W/cm2 irradiation cycles; dark-light cycles over 900-5400 s

Temperature: not reported
Atmosphere: not specified in section; likely same conductance setup
Geometry: two-probe crystal device
Context: AgNC-loaded Rb-CD-MOF
Measurement source: 12 · Section 7 · Figure S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
First high-intensity cycle peak conductivity	~3.5 x 10^-7 S/cm under 1.48 W/cm2	—	—	Figure Axis Approximate	S12 · Section 7 · Figure S7
High-intensity cycling repeatability	dark-light cycles do not give repeatable readings; irreversible changes indicated	—	—	Caption Qualitative	S12 · Section 7 · Figure S7

light-intensity-dependent I-V conductivity

Electrical conductivity

AgNC@Rb-CD-MOF from 10 mM AgNO3 · Single Crystal

Constant temperature 352 K; white-light intensity varied from 314 to 595 mW/cm2 and beyond in Figure 3d

Temperature: 352
Atmosphere: vacuum <0.1 mTorr
Geometry: two-probe single-crystal device in MMR chamber
Context: AgNC-loaded Rb-CD-MOF
Measurement source: 3-4 · Results and Discussion · Figure 3b,d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
AgNC@Rb-CD-MOF conductivity at 314 mW/cm2 and 352 K	3.6 x 10^-9 S/cm	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 3b,d
AgNC@Rb-CD-MOF conductivity at 595 mW/cm2 and 352 K	1.47 x 10^-8 S/cm	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 3b,d

conductivity versus AgNC volume fraction plot

Electrical conductivity

AgNC@Rb-CD-MOF from 2 mM AgNO3 · Single Crystal

Samples prepared from 2, 5 and 10 mM AgNO3; conductivity measured under 430 mW/cm2 light irradiation

Temperature: not specified for Figure S8
Atmosphere: as described for other samples in main text
Geometry: two-probe crystal device
Context: AgNC-loaded Rb-CD-MOF series
Measurement source: 12 · Section 8 · Figure S8

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ln(sigma) high Ag loading under 430 mW/cm2	~ -20.0 at (V%)-1/3 ~4.15	—	—	Figure Axis Approximate	S12 · Section 8 · Figure S8
ln(sigma) low Ag loading under 430 mW/cm2	~ -22.55 at (V%)-1/3 ~5.3	—	—	Figure Axis Approximate	S12 · Section 8 · Figure S8
ln(sigma) medium Ag loading under 430 mW/cm2	~ -20.9 at (V%)-1/3 ~4.6	—	—	Figure Axis Approximate	S12 · Section 8 · Figure S8

temperature-dependent I-V conductivity and Arrhenius analysis

Electrical conductivity

AgNC@Rb-CD-MOF from 10 mM AgNO3 · Single Crystal

Constant light intensity 314 mW/cm2; sample temperature varied using heating stage and K20 controller

Temperature: 330-350 K range reported; Arrhenius range shown in Figure 3e
Atmosphere: vacuum <0.1 mTorr
Geometry: two-probe single-crystal device in MMR chamber
Context: AgNC-loaded Rb-CD-MOF
Measurement source: 3-4 · Results and Discussion · Figure 3a,c,e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Dark activation energy	0.92 eV	—	—	Text Rounded Reported	4 · Results and Discussion · Figure 3f
Activation energy under 314 mW/cm2 light	0.77 eV	—	—	Text Rounded Reported	4 · Results and Discussion · Figure 3e
AgNC@Rb-CD-MOF conductivity at 330 K, 314 mW/cm2	6.8 x 10^-10 S/cm at 330 K	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 3a,c
AgNC@Rb-CD-MOF conductivity at 350 K, 314 mW/cm2	3.1 x 10^-9 S/cm at 350 K	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 3a,c
Temperature dependence rate at 314 mW/cm2	7.7% per deg C	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 3c

two-probe I-V conductance/conductivity using silver paste electrodes and Keithley 6517B

Electrical conductivity

AgNC@Rb-CD-MOF from 10 mM AgNO3 · Single Crystal

High-vacuum MMR chamber <0.1 mTorr; AgNC@Rb-CD-MOF from 10 mM AgNO3; dark and white-light irradiation

Temperature: varied; light heating noted
Atmosphere: vacuum <0.1 mTorr
Geometry: two opposite facets of ca. 100 um thick crystal contacted by silver paste; I-V typically -20 V to +20 V
Context: AgNC-loaded single crystal
Measurement source: 3 · Results and Discussion · Figure 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
AgNC@Rb-CD-MOF dark conductivity (10 mM AgNO3)	~2 x 10^-11 S cm^-1	—	—	Text Approximate	3 · Results and Discussion · Figure 2
AgNC@Rb-CD-MOF dark conductivity in Figure 2b	~2 x 10^-11 S cm^-1 in dark	—	—	Caption Approximate	3 · Results and Discussion · Figure 2b
AgNC@Rb-CD-MOF conductivity at 630 mW/cm2	1.8 x 10^-8 S cm^-1 under light irradiation (630 mW/cm2)	—	—	Caption Rounded Reported	3 · Results and Discussion · Figure 2b
AgNC@Rb-CD-MOF conductivity under 1.48 W/cm2Marked as a best value within this paper	2.15 x 10^-7 S cm^-1	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 2

two-probe I-V photoconductance/conductivity of thin film

Electrical conductivity

AgNC@MIL-53 thin-film device on glass with Au electrodes · Thin Film

AgNC@MIL-53 film; dark at 298, 326 and 352 K; photocurrent at 326 and 352 K under 595 mW/cm2 white light

Temperature: 298, 326, 352
Atmosphere: not reported
Geometry: AgNC@MIL-53 film on glass with Au electrodes
Context: AgNC-loaded MIL-53 film
Measurement source: 5-6 · Results and Discussion · Figure 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
AgNC@MIL-53 dark conductivity at 326 K	7.52 x 10^-9 S/cm	—	—	Text Exact Reported	6 · Results and Discussion · Figure 5
AgNC@MIL-53 illuminated conductivity at 326 K, 595 mW/cm2	3.24 x 10^-8 S/cm	—	—	Text Exact Reported	6 · Results and Discussion · Figure 5
AgNC@MIL-53 dark conductivity at 352 K	1.19 x 10^-8 S/cm	—	—	Text Exact Reported	6 · Results and Discussion · Figure 5
AgNC@MIL-53 illuminated conductivity at 352 K, 595 mW/cm2	2.67 x 10^-7 S/cm	—	—	Text Exact Reported	6 · Results and Discussion · Figure 5
AgNC@MIL-53 photoconductivity factor at 326 K	4.3 times increase	—	—	Text Rounded Reported	6 · Results and Discussion · Figure 5
AgNC@MIL-53 photoconductivity factor at 352 K	22.3 times increase	—	—	Text Rounded Reported	6 · Results and Discussion · Figure 5

two-probe I-V conductance/conductivity using silver paste electrodes and Keithley 6517B

Electrical conductivity

Blank Rb-CD-MOF single crystals · Single Crystal

High-vacuum MMR chamber <0.1 mTorr; dark and white-light irradiation up to 1.48 W/cm2

Temperature: not fixed; light heating noted
Atmosphere: vacuum <0.1 mTorr
Geometry: two opposite crystal facets covered with thin (~hundreds um) conductive quick-drying silver paste
Context: pristine control
Measurement source: 3 · Results and Discussion · Figure 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Blank Rb-CD-MOF dark conductivity	~10^-12 S cm^-1	—	—	Text Approximate	3 · Results and Discussion · Figure 2
Blank Rb-CD-MOF conductivity under 1.48 W/cm2	~2 x 10^-11 S cm^-1 upon 1.48 W/cm2 irradiation	—	—	Text Approximate	3 · Results and Discussion · Figure 2