Electrical Transport — Giant Enhancement of Carrier Mobility in Bimetallic Coordination Polymers

Measurement evidence

Electrical Transport

Giant Enhancement of Carrier Mobility in Bimetallic Coordination Polymers · Dhara B., Kumar V., Gupta K. et al. · ACS Omega · 2017 · 4488-4493

14 measurement groups · 37 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

electrochemical impedance spectroscopy (EIS)

Cr-BTC xerogel pressed pellet · Pellet

Pressed pellet clipped between copper disks; PARSTAT MC PMC-2000, two-electrode setup, 1-100 MHz; Nyquist data fitted with modified Randle circuit.

Geometry
pressed pellet between copper disks
Context
pristine monometallic control
Measurement source
p004-p005 · Results and Discussion; Materials and Methods · Figure 7c,d
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
EIS-derived conductivity~5.0 x 10^-8 S cm-1Text
Approximate
p004 · Results and Discussion · Figure 7c

electrochemical impedance spectroscopy (EIS)

Fe-BTC xerogel pressed pellet · Pellet

Pressed pellet clipped between copper disks; PARSTAT MC PMC-2000, two-electrode setup, 1-100 MHz; Nyquist data fitted with modified Randle circuit.

Geometry
pressed pellet between copper disks
Context
pristine monometallic control
Measurement source
p004-p005 · Results and Discussion; Materials and Methods · Figure 7a,d
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
EIS-derived conductivity~3.0 x 10^-6 S cm-1Text
Approximate
p004 · Results and Discussion · Figure 7a

electrochemical impedance spectroscopy (EIS)

Fe-BTC-Cr 1:1 xerogel pressed pellet · Pellet

Pressed pellet clipped between copper disks; PARSTAT MC PMC-2000, two-electrode setup, 1-100 MHz; Nyquist data fitted with modified Randle circuit.

Geometry
pressed pellet between copper disks
Context
pristine bimetallic framework
Measurement source
p004-p005 · Results and Discussion; Materials and Methods · Figure 7b,d
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
EIS-derived conductivityMarked as a best value within this paper~1.5 x 10^-4 S cm-1Text
Approximate
p004 · Results and Discussion · Figure 7b

four-probe dc electrical conductivity

Cr-BTC xerogel pressed pellet · Pellet

Room-temperature four-probe dc measurement on pressed xerogel pellet using Keithley 6221 and 2182A.

Temperature
room temperature
Geometry
pressed bar-shaped pellet with gold-wire contacts
Context
pristine monometallic control
Measurement source
p003-p005 · Results and Discussion; Materials and Methods · Figure 5a; Figure S5; Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
dc conductivity from reported resistivity1/(3.4 x 10^6 ohm cm) = 2.9 x 10^-7 S/cmCalculated From Reported
Rounded Reported
p004 · Results and Discussion · Table 1

four-probe dc electrical conductivity

Fe-BTC xerogel pressed pellet · Pellet

Room-temperature four-probe dc measurement on pressed xerogel pellet using Keithley 6221 and 2182A.

Temperature
room temperature
Geometry
pressed bar-shaped pellet with gold-wire contacts
Context
pristine monometallic control
Measurement source
p003-p005 · Results and Discussion; Materials and Methods · Figure 5a; Figure S5; Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
dc conductivity from reported resistivity1/(3.3 x 10^4 ohm cm) = 3.0 x 10^-5 S/cmCalculated From Reported
Rounded Reported
p004 · Results and Discussion · Table 1

four-probe dc electrical conductivity

Fe-BTC-Cr 1:1 xerogel pressed pellet · Pellet

Room-temperature four-probe dc measurement on pressed xerogel pellet.

Temperature
room temperature
Geometry
pressed bar-shaped pellet with gold-wire contacts
Context
pristine bimetallic framework
Measurement source
p003-p004 · Results and Discussion · Figure 5a; Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
conductivity response to 1 sun irradiationno appreciable change in conductivity under 1 sun intensity lightText
Qualitative
p004 · Results and Discussion
dc conductivity from reported resistivityMarked as a best value within this paper1/(1 x 10^3 ohm cm) = 1 x 10^-3 S/cmCalculated From Reported
Rounded Reported
p003-p004 · Results and Discussion · Table 1; Figure 5a
SI Table S2 Fe-BTC-Cr conductivity comparison value1.0 x 10^-4 (pellet, 4-probe)SI Table
Rounded Reported
p008 · Supporting Information · Table S2

four-probe dc electrical conductivity

Fe-BTC-Cr 1:2 xerogel pressed pellet · Pellet

Room-temperature four-probe dc measurement on pressed xerogel pellet.

Temperature
room temperature
Geometry
pressed bar-shaped pellet with gold-wire contacts
Context
pristine bimetallic framework
Measurement source
p003-p004 · Results and Discussion · Figure 5a; Table 1; Figure S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
dc conductivity from reported resistivity1/(4.0 x 10^4 ohm cm) = 2.5 x 10^-5 S/cmCalculated From Reported
Rounded Reported
p004 · Results and Discussion · Table 1

four-probe dc electrical conductivity

Fe-BTC-Cr 2:1 xerogel pressed pellet · Pellet

Room-temperature four-probe dc measurement on pressed xerogel pellet.

Temperature
room temperature
Geometry
pressed bar-shaped pellet with gold-wire contacts
Context
pristine bimetallic framework
Measurement source
p003-p004 · Results and Discussion · Figure 5a; Table 1; Figure S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
dc conductivity from reported resistivity1/(3.9 x 10^4 ohm cm) = 2.6 x 10^-5 S/cmCalculated From Reported
Rounded Reported
p004 · Results and Discussion · Table 1

room-temperature I-V / four-probe conductivity

1:1 Fe-BTC + Cr-BTC mechanical mixture pressed pellet · Pellet

Room-temperature current-voltage measurement of pressed mechanical mixture pellet.

Temperature
room temperature
Geometry
pressed pellet
Context
mechanical mixture control
Measurement source
p003 · Results and Discussion · Figure S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
dc conductivity of mechanical mixture~10^-6 S cm-1Text
Approximate
p003 · Results and Discussion · Figure S5

Hall effect measurement, five-probe method in Quantum Design PPMS-Evercool II

Cr-BTC xerogel pressed pellet · Pellet

Room-temperature Hall measurements on bar-shaped pressed pellet with gold-wire contacts; anomalous Hall contribution fitted using RH = RH0 + C/B.

Temperature
300
Geometry
five-probe contact, bar-shaped pressed pellet
Context
pristine monometallic control
Measurement source
p004 · Results and Discussion · Table 1; Figure 6; Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
carrier density7.6 x 10^13 cm^-3Table
Rounded Reported
p004 · Results and Discussion · Table 1
carrier mobility2.4 x 10^-3 cm2 V-1 s-1Table
Rounded Reported
p004 · Results and Discussion · Table 1
ordinary Hall coefficient RH0-8 x 10^4 cm3 C-1Table
Rounded Reported
p004 · Results and Discussion · Table 1
resistivity3.4 x 10^6 ohm cmTable
Rounded Reported
p004 · Results and Discussion · Table 1
semiconductor typen-typeTable
Qualitative
p004 · Results and Discussion · Table 1

Hall effect measurement, five-probe method in Quantum Design PPMS-Evercool II

Fe-BTC xerogel pressed pellet · Pellet

Room-temperature Hall measurements on bar-shaped pressed pellet with gold-wire contacts; anomalous Hall contribution fitted using RH = RH0 + C/B.

Temperature
300
Geometry
five-probe contact, bar-shaped pressed pellet
Context
pristine monometallic control
Measurement source
p004 · Results and Discussion · Table 1; Figure 6; Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
carrier density6.2 x 10^15 cm^-3Table
Rounded Reported
p004 · Results and Discussion · Table 1
carrier mobility3 x 10^-2 cm2 V-1 s-1Table
Rounded Reported
p004 · Results and Discussion · Table 1
ordinary Hall coefficient RH01 x 10^3 cm3 C-1Table
Rounded Reported
p004 · Results and Discussion · Table 1
resistivity3.3 x 10^4 ohm cmTable
Rounded Reported
p004 · Results and Discussion · Table 1
semiconductor typep-typeTable
Qualitative
p004 · Results and Discussion · Table 1

Hall effect measurement, five-probe method in Quantum Design PPMS-Evercool II

Fe-BTC-Cr 1:1 xerogel pressed pellet · Pellet

Room-temperature Hall measurements on bar-shaped pressed pellet with gold-wire contacts; anomalous Hall contribution fitted using RH = RH0 + C/B.

Temperature
300
Geometry
five-probe contact, bar-shaped pressed pellet
Context
pristine bimetallic framework
Measurement source
p004 · Results and Discussion · Table 1; Figure 6; Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
carrier density4.2 x 10^14 cm^-3Table
Rounded Reported
p004 · Results and Discussion · Table 1
carrier mobilityMarked as a best value within this paper15 cm2 V-1 s-1Table
Exact Reported
p004 · Results and Discussion · Table 1
ordinary Hall coefficient RH0-1 x 10^4 cm3 C-1Table
Rounded Reported
p004 · Results and Discussion · Table 1
resistivityMarked as a best value within this paper1 x 10^3 ohm cmTable
Rounded Reported
p004 · Results and Discussion · Table 1
semiconductor typen-typeTable
Qualitative
p004 · Results and Discussion · Table 1
SI comparative carrier mobility rowMarked as a best value within this paper15 cm2/V.s; Our WorkSI Table
Exact Reported
p005 · Supporting Information · Table S1

Hall effect measurement, five-probe method in Quantum Design PPMS-Evercool II

Fe-BTC-Cr 1:2 xerogel pressed pellet · Pellet

Room-temperature Hall measurements on bar-shaped pressed pellet with gold-wire contacts; anomalous Hall contribution fitted using RH = RH0 + C/B.

Temperature
300
Geometry
five-probe contact, bar-shaped pressed pellet
Context
pristine bimetallic framework
Measurement source
p004 · Results and Discussion · Table 1; Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
carrier density2.8 x 10^13 cm^-3Table
Rounded Reported
p004 · Results and Discussion · Table 1
carrier mobility5.5 cm2 V-1 s-1Table
Exact Reported
p004 · Results and Discussion · Table 1
ordinary Hall coefficient RH0-2 x 10^5 cm3 C-1Table
Rounded Reported
p004 · Results and Discussion · Table 1
resistivity4.0 x 10^4 ohm cmTable
Rounded Reported
p004 · Results and Discussion · Table 1
semiconductor typen-typeTable
Qualitative
p004 · Results and Discussion · Table 1

Hall effect measurement, five-probe method in Quantum Design PPMS-Evercool II

Fe-BTC-Cr 2:1 xerogel pressed pellet · Pellet

Room-temperature Hall measurements on bar-shaped pressed pellet with gold-wire contacts; anomalous Hall contribution fitted using RH = RH0 + C/B.

Temperature
300
Geometry
five-probe contact, bar-shaped pressed pellet
Context
pristine bimetallic framework
Measurement source
p004 · Results and Discussion · Table 1; Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
carrier density2.5 x 10^14 cm^-3Table
Rounded Reported
p004 · Results and Discussion · Table 1
carrier mobility0.63 cm2 V-1 s-1Table
Exact Reported
p004 · Results and Discussion · Table 1
ordinary Hall coefficient RH02 x 10^4 cm3 C-1Table
Rounded Reported
p004 · Results and Discussion · Table 1
resistivity3.9 x 10^4 ohm cmTable
Rounded Reported
p004 · Results and Discussion · Table 1
semiconductor typep-typeTable
Qualitative
p004 · Results and Discussion · Table 1