cMOF Evidence Base

Synthesis evidence

Giant Enhancement of Carrier Mobility in Bimetallic Coordination Polymers

Dhara B., Kumar V., Gupta K. et al. · ACS Omega · 2017 · 4488-4493

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Both

Route 1: Other

p005 · Materials and Methods

Metal precursorschromium nitrate
Linker precursorsBTC
Solventsethanol
Atmospherenot reported
Temperature80
Time4
Work-upBTC and chromium nitrate ethanol solutions mixed with sonication and kept at 80 C for 4 h; xerogel isolated by drying under vacuum at room temperature
Activationvacuum drying at room temperature
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcechromium nitrate80.0 mg, 0.2 mmolp005 · Materials and Methods
LinkerBTC42.4 mg, 0.2 mmolp005 · Materials and Methods
Solventethanol0.5 mL each solutionp005 · Materials and Methods
Partial recipeSource: Both

Route 2: Other

p005 · Materials and Methods

Metal precursorsferric nitrate
Linker precursorsBTC
Solventsethanol
Atmospherenot reported
Temperatureroom temperature for gelation/drying; no heating step reported for Fe-BTC in this recipe
Timenot reported
Work-upmixed with sonication to form gel; xerogel isolated by drying under vacuum at room temperature
Activationvacuum drying at room temperature
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourceferric nitrate0.6 mmol (242.4 mg)p005 · Materials and Methods
LinkerBTC0.6 mmol (126.0 mg)p005 · Materials and Methods
Solventethanol4 mL for each solutionp005 · Materials and Methods
Partial recipeSource: Both

Route 3: Other

p005 · Materials and Methods

Metal precursorsmixed ferric nitrate/chromium nitrate = 1:1
Linker precursorsBTC
Solventsethanol
Atmospherenot reported
Temperatureroom temperature
Timenot reported
Work-upmixed metal and BTC ethanol solutions rapidly mixed and kept at room temperature; xerogel isolated by drying under vacuum at room temperature
Activationvacuum drying at room temperature
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcemixed metal (ferric nitrate/chromium nitrate = 1:1)0.6 mmol total mixed metalp005 · Materials and Methods
LinkerBTC0.6 mmolp005 · Materials and Methods
Solventethanol4 mLp005 · Materials and Methods
Partial recipeSource: Both

Route 4: Other

p002 · Results and Discussion

Metal precursorsFe(III)/Cr(III) nitrate salts = 1:2
Linker precursorsBTC
Solventsethanol
Atmospherenot reported
Temperaturenot fully specified; bimetallic 1:1 route kept at room temperature
Timenot reported
Work-upmixed Fe(III)/Cr(III) nitrate salts with BTC in ethanol; xerogel isolated by drying under vacuum at room temperature
Activationvacuum drying at room temperature
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceFe(III)/Cr(III) nitrate salts = 1:2not individually reportedp002 · Results and Discussion
LinkerBTCnot reported for this ratiop002 · Results and Discussion
Solventethanolnot reported for this ratiop002 · Results and Discussion
Partial recipeSource: Both

Route 5: Other

p002 · Results and Discussion

Metal precursorsFe(III)/Cr(III) nitrate salts = 2:1
Linker precursorsBTC
Solventsethanol
Atmospherenot reported
Temperaturenot fully specified; bimetallic 1:1 route kept at room temperature
Timenot reported
Work-upmixed Fe(III)/Cr(III) nitrate salts with BTC in ethanol; xerogel isolated by drying under vacuum at room temperature
Activationvacuum drying at room temperature
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceFe(III)/Cr(III) nitrate salts = 2:1not individually reportedp002 · Results and Discussion
LinkerBTCnot reported for this ratiop002 · Results and Discussion
Solventethanolnot reported for this ratiop002 · Results and Discussion