cMOF Evidence Base
Electrochemistry Application — Charge Transfer-Induced Molecular Hole Doping into Thin Film of Metal-Organic Frameworks

Measurement evidence

Electrochemistry Application

Charge Transfer-Induced Molecular Hole Doping into Thin Film of Metal-Organic Frameworks · Lee D.Y., Kim E.-K., Shrestha N.K. et al. · ACS Applied Materials and Interfaces · 2015 · 18501-18507

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry and optical band-gap estimation

Voltammetry

Iodine-doped Co3(NDC)3 LbL film on ITO · Thin Film

CV of LbL and DB Co3(NDC)3 films on ITO under Ar in 0.1 M tetra-n-butylammonium tetrafluoroborate/acetonitrile; HOMO from oxidation onset and LUMO from HOMO plus band gap.

Atmosphere
Ar
Geometry
MOF film on ITO working electrode; Pt counter; Ag/AgCl reference
Context
Iodine-doped and pristine film energetics
Measurement source
S12 · Figure S8 · Figure S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
HOMO energy level versus vacuum-6.2 eV versus vacuum——Text
Exact Reported		18505 · Results and Discussion · Figure S8
LUMO energy level versus vacuumabout -3.9 eV—aboutCalculated From Reported
Approximate		18505 · Results and Discussion
Calculated band gap of iodine-doped Co3(NDC)3about 2.1 eV—aboutText
Approximate		18505 · Results and Discussion · Figure S7
Experimental optical band gap of iodine-doped Co3(NDC)3Marked as a best value within this paperabout 2.2 eV—aboutText
Approximate		18505 · Results and Discussion · Figure S7

Incident photon-to-current efficiency / EQE spectrum

Photoresponse and photoelectrochemistry

Iodine-doped Co3(NDC)3 sensitised TiO2/FTO Graetzel-type cell · Electrode

TiO2-based Graetzel-type cell with Co3(NDC)3 LbL layer, comparing undoped and iodine-doped Co MOF light-harvesting layer.

Geometry
FTO/TiO2(HBL)/TiO2/Co MOF or Co MOF_I2/Pt
Context
Application composite with pristine-control device trace
Measurement source
S14 · Figure S10 · Figure S10
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Maximum IPCE/EQE for iodine-doped Co3(NDC)3/TiO2 cellMarked as a best value within this paperapproximately 9.2% at about 560 nm from Figure S109.2 %visual estimate from rendered SI plotFigure Axis
Approximate		S14 · Figure S10 · Figure S10
IPCE/EQE for undoped Co3(NDC)3/TiO2 controlapproximately 0% across 300-850 nm0 %visual estimate from rendered SI plotFigure Axis
Approximate		S14 · Figure S10 · Figure S10