Spectroscopy — Vertical Conductive Metal–Organic Framework Single-Crystalline Nanowire Arrays for Efficient Electrocatalytic Hydrogen Evolution

2 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ag-MOF-NWs · Single Crystal

Bond evolution during Ag-BHT coordination reaction; BHT compared with Ag-MOF-NWs.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag-MOF-NWs Raman Ag-Ag peak	179.2 cm-1	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure 4a
BHT Raman C=C peak	1477.4 cm-1	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure 4a
BHT Raman overlapped C-C/C-S peak	1136.3 cm-1	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure 4a
BHT Raman S-H peak	2501.1 cm-1	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure 4a
BHT Raman S-S peak	460.2 cm-1	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure 4a
Ag-MOF-NWs Raman S-Ag peak	303.5 cm-1	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure 4a
S-H peak after Ag-MOF formation	complete disappearance of the S-H peak	—	—	Text Qualitative	4 · Synthesis and Characterization of Materials · Figure 4a

Ag-MOF-NWs · Single Crystal

Bond types and elementary compositions of Ag-MOF-NWs from survey and Ag 3d/S 2p spectra.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
XPS Ag 3d3/2 binding energy	374.5 eV	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure S5
XPS Ag 3d5/2 binding energy	368.4 eV	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure S5
S 2p spin-orbit splitting	1.2 eV	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure S5
XPS S-Ag 2p1/2 binding energy	164.5 eV	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure S5
XPS S-Ag 2p3/2 binding energy	163.3 eV	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure S5
XPS S-C 2p1/2 binding energy	163.3 eV	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure S5
XPS S-C 2p3/2 binding energy	162.1 eV	—	—	Text Exact Reported	4 · Synthesis and Characterization of Materials · Figure S5