Electrical Transport — Electron-Conductive Metal-Organic Framework, Fe(dhbq)(dhbq = 2,5-Dihydroxy-1,4-benzoquinone): Coexistence of Microporosity and Solid-State Redox Activity

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Fe(dhbq) compressed pellet · Pellet

Constant voltage 1.0 V using Keithley 2600 sourcemeter; PPMS temperature control; Arrhenius fit

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
activation energy EaMarked as a best value within this paper	0.32 eV	—	—	Text Exact Reported	3 · Results and Discussion · Figure 7b
temperature-dependent transport behaviour	semiconductive behavior	—	—	Text Qualitative	3 · Results and Discussion · Figure 7b
transport limitation mechanism	limited by something extrinsic, such as hopping through defect sites	—	—	Text Qualitative	4 · Results and Discussion

Fe(dhbq) compressed pellet · Pellet

293 K compressed pellet with carbon paste contacts and gold wires

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrical conductivity Fe(dhbq)Marked as a best value within this paper	5 x 10^-6 S cm^-1	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 7
conductivity increase upon desolvation	10^4 times	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 7
electrical resistivity Fe(dhbq)Marked as a best value within this paper	2 x 10^5 ohm cm	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 7

Fe(dhbq)(H2O)2 compressed pellet · Pellet

293 K compressed pellet with carbon paste contacts and gold wires

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrical resistivity Fe(dhbq)(H2O)2Marked as a best value within this paper	1 x 10^9 ohm cm	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 7