Porosity — Electron-Conductive Metal-Organic Framework, Fe(dhbq)(dhbq = 2,5-Dihydroxy-1,4-benzoquinone): Coexistence of Microporosity and Solid-State Redox Activity

6 measurement groups · 17 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Anhydrous Fe(dhbq) powder · Powder

25 C; Fe(dhbq).nH2O initially n = 0; P/P0 up to 0.65 and 1.0

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
water adsorption first plateau	n = 0.3 at P/P0 = 0.1	—	—	Text Approximate	14 · Water vapor adsorption isotherm · Figure S11
water adsorption reversibility limit	fully reversible up to P/P0 = 0.65	—	—	Text Exact Reported	14 · Water vapor adsorption isotherm · Figure S11
water adsorption second plateau	n = 1.2-1.4 at 0.3 < P/P0 < 0.65	—	—	Text Range	14 · Water vapor adsorption isotherm · Figure S11
water adsorption structural-change step	P/P0 = 0.95	—	—	Text Exact Reported	14 · Water vapor adsorption isotherm · Figure S11

Anhydrous Fe(dhbq) powder · Powder

77 K N2 isotherm; Langmuir surface area; Horvath-Kawazoe pore size

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
N2 isotherm type Fe(dhbq)	type I	—	—	Text Qualitative	3 · Results and Discussion · Figure 5
pore diameter Fe(dhbq)	4.4 A	—	—	Text Exact Reported	4 · Results and Discussion
Horvath-Kawazoe pore size Fe(dhbq)Marked as a best value within this paper	0.44 nm	—	—	Text Exact Reported	3 · Results and Discussion · Figure 5
Langmuir surface area Fe(dhbq)Marked as a best value within this paper	497 m2 g-1	—	—	Text Rounded Reported	3 · Results and Discussion · Figure 5
Langmuir surface area Fe(dhbq) SI	498 m2 g-1	—	—	SI Table Exact Reported	10 · N2 adsorption isotherms · Table S2
adsorbed volume Vm Fe(dhbq)	114.3 cm3 g-1	—	—	SI Table Exact Reported	10 · N2 adsorption isotherms · Table S2

Fe(dhbq)(H2O)2 polycrystalline powder · Powder

77 K N2 isotherm control for hydrated sample

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
porosity of Fe(dhbq)(H2O)2	no porosity	—	—	Text Qualitative	3 · Results and Discussion · Figure S6

Mg(dhbq) powder · Powder

N2 isotherm and Langmuir surface area for M(dhbq), M = Mg

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Langmuir surface area MG(dhbq)	474 m2 g-1	—	—	SI Table Exact Reported	10 · N2 adsorption isotherms · Table S2
adsorbed volume Vm MG(dhbq)	108.8 cm3 g-1	—	—	SI Table Exact Reported	10 · N2 adsorption isotherms · Table S2

Mn(dhbq) powder · Powder

N2 isotherm and Langmuir surface area for M(dhbq), M = Mn

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Langmuir surface area MN(dhbq)	495 m2 g-1	—	—	SI Table Exact Reported	10 · N2 adsorption isotherms · Table S2
adsorbed volume Vm MN(dhbq)	113.7 cm3 g-1	—	—	SI Table Exact Reported	10 · N2 adsorption isotherms · Table S2

Zn(dhbq) powder · Powder

N2 isotherm and Langmuir surface area for M(dhbq), M = Zn

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Langmuir surface area ZN(dhbq)	410 m2 g-1	—	—	SI Table Exact Reported	10 · N2 adsorption isotherms · Table S2
adsorbed volume Vm ZN(dhbq)	94.1 cm3 g-1	—	—	SI Table Exact Reported	10 · N2 adsorption isotherms · Table S2