Electrochemistry Application — Electron-Conductive Metal-Organic Framework, Fe(dhbq)(dhbq = 2,5-Dihydroxy-1,4-benzoquinone): Coexistence of Microporosity and Solid-State Redox Activity

9 measurement groups · 48 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

charge-discharge reference

Galvanostatic cycling

Acetylene black charge-discharge reference · Electrode

AB-only charge-discharge used to estimate double-layer capacity contribution

Measurement source: 19 · Discussion about capacity contribution of AB · Figure S18; Tables S3-S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
AB specific capacitance	3 mA h g^-1 V^-1	—	—	Text Exact Reported	19 · Discussion about capacity contribution of AB · Figure S18
AB contribution first discharge, Table S3, 10% Fe(dhbq)	36 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S3
AB contribution first discharge, Table S3, 50% Fe(dhbq)	3.6 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S3
AB contribution first discharge, Table S3, 80% Fe(dhbq)	0.6 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S3
AB contribution other cycles, Table S3, 10% Fe(dhbq)	60 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S3
AB contribution other cycles, Table S3, 50% Fe(dhbq)	6.0 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S3
AB contribution other cycles, Table S3, 80% Fe(dhbq)	0.9 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S3
AB contribution first discharge, Table S4, 10% Fe(dhbq)	32 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S4
AB contribution first discharge, Table S4, 50% Fe(dhbq)	4.0 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S4
AB contribution first discharge, Table S4, 80% Fe(dhbq)	2.6 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S4
AB contribution other cycles, Table S4, 10% Fe(dhbq)	60 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S4
AB contribution other cycles, Table S4, 50% Fe(dhbq)	6.4 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S4
AB contribution other cycles, Table S4, 80% Fe(dhbq)	5.1 mA h g^-1	—	—	SI Table Exact Reported	20 · Discussion about capacity contribution of AB · Table S4

solid-state cyclic voltammetry

Voltammetry

Fe(dhbq) 50 wt% / AB 40 wt% / PTFE 10 wt% cathode · Electrode

1.5-4.0 V vs Li/Li+; scan rate 0.5 mV/s; Fe(dhbq) 50 wt%, AB 40 wt%, PTFE 10 wt%

Measurement source: 4 · Results and Discussion · Figure 8a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
solid-state CV oxidation peak	2.4 V vs Li/Li+	—	—	Text Exact Reported	4 · Results and Discussion · Figure 8a
solid-state CV reduction peakMarked as a best value within this paper	2.1 V vs Li/Li+	—	—	Text Exact Reported	4 · Results and Discussion · Figure 8a
CV scan rate	0.5 mV s^-1	—	—	Caption Exact Reported	4 · Results and Discussion · Figure 8
Fe(II)/Fe(III) redox in CV	no redox peaks observed in 1.5-4.0 V range	—	—	Text Qualitative	4 · Results and Discussion · Figure 8a

cycle performance

Fe(dhbq) 45 wt% / AB 45 wt% / PTFE 10 wt% cathode · Electrode

1.5-3.5 V; 0.3 C (84 mA/g); Fe(dhbq) 45 wt%, AB 45 wt%, PTFE 10 wt%

Measurement source: 22 · Cycle performance · Figure S22

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1.5-3.5 V cycling coulombic efficiency	~100% after early cycles	—	—	Figure Axis Approximate	22 · Cycle performance · Figure S22
1.5-3.5 V cycling 19th discharge capacity	~75 mA h g^-1	—	—	Figure Axis Approximate	22 · Cycle performance · Figure S22
1.5-3.5 V cycling 1st discharge capacity	~260 mA h g^-1	—	—	Figure Axis Approximate	22 · Cycle performance · Figure S22

cycle performance

Fe(dhbq) 50 wt% / AB 40 wt% / PTFE 10 wt% cathode · Electrode

1.5-4.0 V; 0.1 C (28 mA/g); Fe(dhbq) 50 wt%, AB 40 wt%, PTFE 10 wt%

Measurement source: 22 · Cycle performance · Figure S21

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
cycle performance 1st discharge capacity	~260 mA h g^-1	—	—	Figure Axis Approximate	22 · Cycle performance · Figure S21
cycle performance 30th discharge capacity	~135 mA h g^-1	—	—	Figure Axis Approximate	22 · Cycle performance · Figure S21
cycle performance 30th coulombic efficiency	~90%	—	—	Figure Axis Approximate	22 · Cycle performance · Figure S21

galvanostatic charge-discharge

Galvanostatic cycling

Fe(dhbq) 50 wt% / AB 40 wt% / PTFE 10 wt% cathode · Electrode

0.25 C (70 mA/g); Fe(dhbq) 50 wt%, AB 40 wt%, PTFE 10 wt%

Measurement source: 18 · Charge-Discharge characteristics · Figure S16

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
0.25 C 30th discharge capacity visual estimate	~135 mA h g^-1	—	—	Figure Axis Approximate	18 · Charge-Discharge characteristics · Figure S16
0.25 C first discharge capacity visual estimate	~250 mA h g^-1	—	—	Figure Axis Approximate	18 · Charge-Discharge characteristics · Figure S16

galvanostatic charge-discharge

Galvanostatic cycling

Fe(dhbq) 45 wt% / AB 45 wt% / PTFE 10 wt% cathode · Electrode

0.3 C (84 mA/g); 1.5-3.5 V; Fe(dhbq) 45 wt%, AB 45 wt%, PTFE 10 wt%

Measurement source: 18 · Charge-Discharge characteristics · Figure S17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
0.3 C 10th discharge capacity visual estimate	~95 mA h g^-1	—	—	Figure Axis Approximate	18 · Charge-Discharge characteristics · Figure S17
0.3 C first discharge capacity visual estimate	~260 mA h g^-1	—	—	Figure Axis Approximate	18 · Charge-Discharge characteristics · Figure S17

galvanostatic charge-discharge

Galvanostatic cycling

Fe(dhbq) 10 wt% / AB 80 wt% / PTFE 10 wt% cathode · Electrode

0.1 C (28 mA/g); variable mixing ratio Fe(dhbq) 10 wt%, AB 80 wt%, PTFE 10 wt%

Measurement source: 4 · Results and Discussion · Table 1; Figure S15

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Table 1 first charge capacity 10% Fe(dhbq)	272 mA h g^-1	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 C1/D1 10% Fe(dhbq)	0.89	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 first discharge capacity 10% Fe(dhbq)	308 mA h g^-1	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 second discharge capacity 10% Fe(dhbq)	260 mA h g^-1	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 D2/C1 10% Fe(dhbq)	0.95	—	—	Table Exact Reported	4 · Results and Discussion · Table 1

galvanostatic charge-discharge

Galvanostatic cycling

Fe(dhbq) 50 wt% / AB 40 wt% / PTFE 10 wt% cathode · Electrode

0.1 C (28 mA/g); 1.5-4.0 V vs Li/Li+; half-cell from discharge; capacities normalised as reported

Measurement source: 4 · Results and Discussion · Figure 8b; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first discharge capacity, 50 wt% Fe(dhbq)Marked as a best value within this paper	264 mA h g^-1	—	—	Text Exact Reported	4 · Results and Discussion · Figure 8b; Table 1
first charge/first discharge ratio	67%	—	—	Text Rounded Reported	4 · Results and Discussion · Table 1
energy density, first discharge	556 mW h g^-1	—	—	Text Exact Reported	4 · Results and Discussion · Figure 8b
first charge capacity, 50 wt% Fe(dhbq)	178 mA h g^-1	—	—	Text Exact Reported	4 · Results and Discussion · Table 1
discharge plateau	2.0-2.2 V vs Li/Li+	—	—	Text Range	4 · Results and Discussion · Figure 8b
Table 1 first charge capacity 50% Fe(dhbq)	178 mA h g^-1	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 C1/D1 50% Fe(dhbq)	0.67	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 first discharge capacity 50% Fe(dhbq)	264 mA h g^-1	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 second discharge capacity 50% Fe(dhbq)	181 mA h g^-1	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 D2/C1 50% Fe(dhbq)	1.02	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
theoretical capacity for two-electron process	276 mA h g^-1	—	—	Text Exact Reported	4 · Results and Discussion

galvanostatic charge-discharge

Galvanostatic cycling

Fe(dhbq) 80 wt% / AB 10 wt% / PTFE 10 wt% cathode · Electrode

0.1 C (28 mA/g); variable mixing ratio Fe(dhbq) 80 wt%, AB 10 wt%, PTFE 10 wt%

Measurement source: 5 · Results and Discussion · Table 1; Figure S15

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Table 1 first charge capacity 80% Fe(dhbq)	91 mA h g^-1	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 C1/D1 80% Fe(dhbq)	0.6	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 first discharge capacity 80% Fe(dhbq)	153 mA h g^-1	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 second discharge capacity 80% Fe(dhbq)	107 mA h g^-1	—	—	Table Exact Reported	4 · Results and Discussion · Table 1
Table 1 D2/C1 80% Fe(dhbq)	1.17	—	—	Table Exact Reported	4 · Results and Discussion · Table 1