Other — Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests

Measurement evidence

Other

Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests · Kung C.-W., Otake K., Buru C.T. et al. · Journal of the American Chemical Society · 2018 · 3871-3875

2 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

EDS elemental line scan and ICP-OES

Elemental microanalysis and mapping Bulk elemental and compositional analysis

NiCB@NU-1000 powder · Powder

EDS line scan across NiCB@NU-1000 crystal; ICP-OES on digested NiCB@NU-1000.

Context: Guest loading and spatial uniformity assessment.
Measurement source: 3872 · results · Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NiCB loading by ICP-OES	0.74 +/- 0.07 NiCB per Zr6 node	—	+/- 0.07	Text Exact Reported	3872 · results
Ni and Zr distributions overlap	NiCB installed uniformly in NU-1000 crystals	—	—	Qualitative Qualitative	3872 · results · Figure S2

PXRD, SEM, ICP-OES, N2 sorption, DFT pore size distribution

X-ray diffraction and scattering Scanning electron microscopy Bulk elemental and compositional analysis Gas sorption and porosity Density functional theory

spin-coated Mn-AIM-NiCB@NU-1000 thin film · Thin Film

Characterisation of Mn-AIM-NU-1000 and Mn-AIM-NiCB@NU-1000 after AIM installation.

Context: Conductive NiCB@NU-1000 scaffold compared with pristine NU-1000 scaffold after Mn oxide installation.
Measurement source: S16 · S8 · Figures S8-S10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area of Mn-AIM-NiCB@NU-1000	695 m2/g	—	—	Text Exact Reported	S16 · S8 · Figure S10a
BET surface area of Mn-AIM-NU-1000	790 m2/g	—	—	Text Exact Reported	S16 · S8 · Figure S10a
Mn loading in Mn-AIM-NiCB@NU-1000	8.2 Mn on each node	—	—	Text Rounded Reported	S16 · S8
Mn loading in Mn-AIM-NU-1000	8.5 Mn on each node	—	—	Text Rounded Reported	S16 · S8
Ni loading after Mn AIM	0.79 Ni on each node	—	—	Text Rounded Reported	S16 · S8