Electrical Transport — Electrically Conductive π-Intercalated Graphitic Metal-Organic Framework Containing Alternate π-Donor/Acceptor Stacks

8 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Temperature-dependent conductivity Arrhenius analysis

Electrical conductivity

Supramolecular [HATP/HCTP]n array powder/crystals · Powder

Temperature-dependent I-V plots and Arrhenius plot for the supramolecular array.

Atmosphere: not specified
Geometry: Pressed pellet
Context: Non-MOF donor/acceptor array model control.
Measurement source: 6 · Results and Discussion · Figure 5c and Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal activation energy of [HATP/HCTP]n array	450 meV	0.45 eV	—	Text Exact Reported	6 · Results and Discussion · Figure 5c

Temperature-dependent conductivity Arrhenius analysis

Electrical conductivity

iGMOF1 pressed pellet · Pellet

Temperature-dependent I-V plots and Arrhenius plot.

Atmosphere: not specified
Geometry: Pressed pellet
Context: Target iGMOF compared to pristine Cu3(HATP)2 literature/control and [HATP/HCTP]n array.
Measurement source: 6 · Results and Discussion · Figure 5b and Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal activation energy of pristine Cu3(HATP)2 comparison	65 meV	0.065 eV	—	Text Exact Reported	6 · Results and Discussion · Figure 5
Thermal activation energy of iGMOF1 conductivityMarked as a best value within this paper	Ea = 36 meV	0.036 eV	—	Text Exact Reported	6 · Results and Discussion · Figure 5b

Two-probe I-V on pressed pellets with Keithley 2400 source meter

Electrical conductivity

Pristine Cu3(HATP)2 pressed pellet · Pellet

Ambient conditions; same pellet protocol as iGMOF1.

Temperature: 293-295
Atmosphere: ambient
Geometry: Pressed pellet between Ag-coated stainless-steel rods
Context: Pristine framework control prepared and measured under same conditions.
Measurement source: 5 · Results and Discussion · Figure 5a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Average bulk electrical conductivity of pristine Cu3(HATP)2	sigma_average = 2.1 (+/- 0.5) S m-1	2.1 S m-1	+/- 0.5 S m-1	Text Rounded Reported	5 · Results and Discussion · Figure 5a
Highest bulk electrical conductivity of pristine Cu3(HATP)2	sigma_highest = 2.7 S m-1	2.7 S m-1	—	Text Rounded Reported	5 · Results and Discussion · Figure 5a

Two-probe I-V on pressed material

Electrical conductivity

Supramolecular [HATP/HCTP]n array powder/crystals · Powder

Ambient pressed-pellet conductivity comparison.

Temperature: 293-295
Atmosphere: ambient
Geometry: Pressed pellet; detailed protocol same as SI conductivity method
Context: Non-MOF donor/acceptor array model control.
Measurement source: 5 · Results and Discussion · Figure 5a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Electrical conductivity of supramolecular [HATP/HCTP]n array	1.8 x 10-5 S m-1	0.000018 S m-1	—	Text Rounded Reported	5 · Results and Discussion · Figure 5a

Two-probe I-V on pressed pellet

Electrical conductivity

Post-synthetically HCTP-treated Cu3(HATP)2 · Powder

Ambient conductivity of post-synthetically HCTP-treated Cu3(HATP)2.

Temperature: 293-295
Atmosphere: ambient
Geometry: Pressed pellet
Context: Attempted post-synthetic intercalation control.
Measurement source: 5 · Results and Discussion · Figure 5a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Electrical conductivity of post-synthetically HCTP-treated Cu3(HATP)2	3.9 S m-1	3.9 S m-1	—	Text Rounded Reported	5 · Results and Discussion · Figure 5a

Two-probe I-V on pressed pellets with Keithley 2400 source meter

Electrical conductivity

iGMOF1 pressed pellet · Pellet

Ambient conditions; pellets made with Ag-paint-coated stainless-steel rods; constant 200 MPa pressure for 1 min.

Temperature: 293-295
Atmosphere: ambient
Geometry: Pressed pellet between Ag-coated stainless-steel rods, rod radius 0.135 cm, area 0.057 cm2
Context: Target guest-loaded iGMOF compared with pristine and attempted-intercalation controls.
Measurement source: S2 · Electrical Conductivity Measurements · Figure 5a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ohmic I-V behaviour	linear current-voltage relationships	—	—	Text Qualitative	5 · Results and Discussion · Figure 5a
Average bulk electrical conductivity of iGMOF1	sigma_average = 25 (+/- 5) S m-1	25 S m-1	+/- 5 S m-1	Text Rounded Reported	5 · Results and Discussion · Figure 5a
Highest bulk electrical conductivity of iGMOF1Marked as a best value within this paper	sigma_highest = 30 S m-1	30 S m-1	—	Text Rounded Reported	5 · Results and Discussion · Figure 5a

Representative I-V plot on pressed pellet

Electrical conductivity

Cu3(HATP)2 formed in the presence of pyrene · Pellet

Cu3(HATP)2 formed in the presence of equimolar pyrene.

Temperature: 293-295
Atmosphere: ambient
Geometry: Pressed pellet
Context: Pi-donor exclusion control.
Measurement source: S10 · Figure S17 · Figure S17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Conductivity of Cu3(HATP)2 formed in the presence of pyrene	sigma = 2.5 (+/- 0.5) S/m	2.5 S m-1	+/- 0.5 S m-1	Figure Axis Rounded Reported	S10 · Figure S17 · Figure S17

Representative I-V plot on pressed pellet

Electrical conductivity

Cu3(HATP)2 formed in the presence of triphenylene · Pellet

Cu3(HATP)2 formed in the presence of equimolar triphenylene.

Temperature: 293-295
Atmosphere: ambient
Geometry: Pressed pellet
Context: Pi-donor exclusion control.
Measurement source: S10 · Figure S17 · Figure S17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Conductivity of Cu3(HATP)2 formed in the presence of triphenylene	sigma = 3.4 (+/- 0.7) S/m	3.4 S m-1	+/- 0.7 S m-1	Figure Axis Rounded Reported	S10 · Figure S17 · Figure S17