Electrochemistry Application — Electrically Conductive π-Intercalated Graphitic Metal-Organic Framework Containing Alternate π-Donor/Acceptor Stacks

Measurement evidence

Electrochemistry Application

Electrically Conductive π-Intercalated Graphitic Metal-Organic Framework Containing Alternate π-Donor/Acceptor Stacks · Yadav A., Zhang S., Benavides P.A. et al. · Angewandte Chemie - International Edition · 2023 · e202303819

1 measurement group · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

iGMOF1 black powder · Powder

Solid-state CV of iGMOF1 and Cu3(HATP)2 drop-cast films on glassy carbon in MeCN; solution CVs of HATP, HCTP, and [HATP/HCTP]n in DMF; 0.1 M Bu4NPF6 vs Ag/AgCl.

Geometry: Drop-cast films on glassy carbon working electrode for solids
Context: Electrochemical evidence for HATP/HCTP donor/acceptor interaction in iGMOF1.
Measurement source: S8 · Figure S10 · Figure S10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Solution CV first oxidation of HATP in [HATP/HCTP]n array	+0.58 V vs Ag/AgCl	0.58 V vs Ag/AgCl	—	Text Rounded Reported	5 · Results and Discussion · Figure S10
Solution CV first reduction of HCTP in [HATP/HCTP]n array	-0.97 V vs Ag/AgCl	-0.97 V vs Ag/AgCl	—	Text Rounded Reported	5 · Results and Discussion · Figure S10
Free HATP first oxidation comparison	+0.49 V vs Ag/AgCl	0.49 V vs Ag/AgCl	—	Text Rounded Reported	5 · Results and Discussion · Figure S10
Free HCTP first reduction comparison	-0.80 V vs Ag/AgCl	-0.8 V vs Ag/AgCl	—	Text Rounded Reported	5 · Results and Discussion · Figure S10
Solid-state CV first oxidation of HATP in iGMOF1	+0.60 V vs Ag/AgCl	0.6 V vs Ag/AgCl	—	Text Rounded Reported	5 · Results and Discussion · Figure S10
Solid-state CV first reduction of HCTP in iGMOF1	-1.1 V vs Ag/AgCl	-1.1 V vs Ag/AgCl	—	Text Rounded Reported	5 · Results and Discussion · Figure S10