cMOF Evidence Base

Synthesis evidence

Chemiresistive Sensor Arrays from Conductive 2D Metal-Organic Frameworks

Campbell M.G., Liu S.F., Swager T.M. et al. · Journal of the American Chemical Society · 2015 · 13780-13783

7 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Vague recipeSource: Both

Route 1: Unknown

SI S2 · Materials and Methods

Linker precursorsHHTP implied by formula; exact reagent recipe not reproduced.
AtmosphereAmbient atmosphere stated for synthetic manipulations in this work, but exact prior synthesis atmosphere is not reproduced.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
LinkerHHTP (2,3,6,7,10,11-hexahydroxytriphenylene)Not specifiedSI S2 · Materials and Methods
Vague recipeSource: Both

Route 2: Unknown

main p002 / article page 13781 · Results

Linker precursorsHITP implied by formula; exact reagent recipe not reproduced.
AtmosphereAmbient atmosphere stated for synthetic manipulations in this work, but exact prior synthesis atmosphere is not reproduced.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
LinkerHITP (2,3,6,7,10,11-hexaiminotriphenylene)Not specifiedmain p002 / article page 13781 · Results
Partial recipeSource: SI

Route 3: Drop Cast

SI S2 · Materials and Methods

Metal precursorsFreshly prepared Cu3(HHTP)2 MOF powder
SolventsAcetone suspension, about 1 mg/mL
AtmosphereDried under nitrogen gas flow after drop-casting
Substrate orientationInterdigitated gold electrodes on corundum substrate (CC1.W1, BVT Technologies)
Work-upIterative drop casting if needed to reach about 10-100 kOhm device resistance; dried under nitrogen.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherFreshly prepared Cu3(HHTP)2~1 mg/mL in acetoneSI S2 · Materials and Methods
SolventacetoneNot specifiedSI S2 · Materials and Methods
Partial recipeSource: SI

Route 4: Drop Cast

SI S2 · Materials and Methods

Metal precursorsFreshly prepared Cu3(HITP)2 MOF powder
SolventsAcetone suspension, about 1 mg/mL
AtmosphereDried under nitrogen gas flow after drop-casting
Substrate orientationInterdigitated gold electrodes on corundum substrate (CC1.W1, BVT Technologies)
Work-upIterative drop casting if needed to reach about 10-100 kOhm device resistance; dried under nitrogen.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherFreshly prepared Cu3(HITP)2~1 mg/mL in acetoneSI S2 · Materials and Methods
SolventacetoneNot specifiedSI S2 · Materials and Methods
Partial recipeSource: SI

Route 5: Drop Cast

SI S2 · Materials and Methods

Metal precursorsFreshly prepared Ni3(HITP)2 MOF powder
SolventsAcetone suspension, about 1 mg/mL
AtmosphereDried under nitrogen gas flow after drop-casting
Substrate orientationInterdigitated gold electrodes on corundum substrate (CC1.W1, BVT Technologies)
Work-upIterative drop casting if needed to reach about 10-100 kOhm device resistance; dried under nitrogen.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherFreshly prepared Ni3(HITP)2~1 mg/mL in acetoneSI S2 · Materials and Methods
SolventacetoneNot specifiedSI S2 · Materials and Methods
Partial recipeSource: SI

Route 6: Other

SI S2 · Materials and Methods · Figure S4

Metal precursorsCompressed pellet of freshly prepared Ni3(HITP)2 MOF 3
SolventsSolvent-free
AtmosphereAmbient atmosphere implied
Substrate orientationWeigh paper substrate with 180 nm Au electrodes and 0.3 mm gap
Work-upMOF pellet abraded by hand into electrode gap until triplicate channels reached about 200-400 MOhm.
Scalability contextManual drawing method demonstrated as solvent-free fabrication on paper substrates.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
OtherCompressed pellet of MOF 3 (Ni3(HITP)2)Not specifiedSI S2 · Materials and Methods · Figure S4
Vague recipeSource: Both

Route 7: Unknown

main p002 / article page 13781 · Results

Linker precursorsHITP implied by formula; exact reagent recipe not reproduced.
AtmosphereAmbient atmosphere stated for synthetic manipulations in this work, but exact prior synthesis atmosphere is not reproduced.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
LinkerHITP (2,3,6,7,10,11-hexaiminotriphenylene)Not specifiedmain p002 / article page 13781 · Results