Electrical Transport — Metal-organic framework nanomaterials as novel signal probes for electron transfer mediated ultrasensitive electrochemical immunoassay

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

AC electrochemical impedance spectroscopy

Impedance spectroscopy

Pt-COFs modified glassy carbon electrode · Electrode

Nyquist impedance spectra in 5 mmol/L [Fe(CN)6]3-/4- for bare GCE, Pt-COFs/GCE, anti-CRP/Pt-COFs/GCE, CRP/anti-CRP/Pt-COFs/GCE, and Au-MOFs-Ab2-CRP/anti-CRP/Pt-COFs/GCE.

Geometry: modified glassy carbon electrode
Context: Pt-COFs compared against bare GCE and stepwise immunosensor assemblies
Measurement source: 5 · Electrochemical Characterization of the Modified GC Electrode · Figure 3; Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Pt-COFs decrease electrode impedance	Pt-COFs/GCE showed decreased electrochemical impedance relative to bare GCE	—	—	Text Qualitative	5 · Electrochemical Characterization of the Modified GC Electrode · Figure 3
relative electronic conductivity improvement by Pt-COFsMarked as a best value within this paper	About 400% percentage of electronic conductivity was improved by using Pt-COFs	—	—	Text Approximate	5 · Electrochemical Characterization of the Modified GC Electrode · Figure S14

cyclic voltammetry redox-probe comparison

Voltammetry

Pt-COFs modified glassy carbon electrode · Electrode

GC electrode and Pt-COFs-modified electrode in 10 mM PBS (pH 7.4) containing 0.1 M KCl and 5 mM K3[Fe(CN)6]/K4[Fe(CN)6].

Geometry: glassy carbon electrode with/without Pt-COFs
Context: Pt-COF composite on GCE compared with bare GCE
Measurement source: 16 · Supporting Information · Figure S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
bare GC anodic redox-probe peak current	approximately 0.00012 A	—	—	Figure Axis Approximate	16 · Supporting Information · Figure S14
bare GC cathodic redox-probe peak current	approximately -0.00010 A	—	—	Figure Axis Approximate	16 · Supporting Information · Figure S14
Pt-COFs/GCE anodic redox-probe peak current	approximately 0.00019 A	—	—	Figure Axis Approximate	16 · Supporting Information · Figure S14
Pt-COFs/GCE cathodic redox-probe peak current	approximately -0.00018 A	—	—	Figure Axis Approximate	16 · Supporting Information · Figure S14