Diffraction Structure — Multimetal Incorporation into 2D Conductive Metal-Organic Framework Nanowires Enabling Excellent Electrocatalytic Oxidation of Benzylamine to Benzonitrile

Measurement evidence

Diffraction Structure

Multimetal Incorporation into 2D Conductive Metal-Organic Framework Nanowires Enabling Excellent Electrocatalytic Oxidation of Benzylamine to Benzonitrile · Wang Y., Xue Y.-Y., Yan L.-T. et al. · ACS Applied Materials and Interfaces · 2020 · 24786-24795

2 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Powder X-ray diffraction (PXRD/XRD), Cu Kalpha

X-ray diffraction and scattering

NiCoFe-CAT nanowire powder · Powder

Series of Ni-CAT, NiCo-CAT, NiFe-CAT, and NiCoFe-CAT compared with simulated Ni-CAT pattern.

Context: Pristine/mixed-metal nanowire powders.
Measurement source: 2 · Experimental Section · Figure 2a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
M-CAT PXRD agreement with simulated Ni-CAT	All M-CAT electrocatalysts are in good agreement with the simulated pattern from crystallographic Ni-CAT.	—	—	Text Qualitative	4 · Results and Discussion · Figure 2a
Weak broad PXRD (001) peak	26.7 deg 2-theta	—	—	Text Rounded Reported	4 · Results and Discussion · Figure 2a
PXRD (100) peak	4.6 deg 2-theta	—	—	Text Rounded Reported	4 · Results and Discussion · Figure 2a
PXRD (200) peak	9.5 deg 2-theta	—	—	Text Rounded Reported	4 · Results and Discussion · Figure 2a
PXRD (210) peak	12.5 deg 2-theta	—	—	Text Rounded Reported	4 · Results and Discussion · Figure 2a

Structural assignment from X-ray crystallography and literature Ni-CAT crystallographic model

X-ray diffraction and scattering

NiCoFe-CAT nanowire powder · Powder

Layer spacing and 1D channel dimensions discussed for M-CAT framework.

Context: Mixed-metal nanowire framework.
Measurement source: 3 · Results and Discussion · Figure 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Benzylamine dynamic diameter for channel comparison	0.7 nm	—	—	Text Rounded Reported	3 · Results and Discussion
1D channel diameter	about 2 nm	—	—	Text Approximate	3 · Results and Discussion · Figure 1
Adjacent layer distance	approximately 3.3 A	—	—	Text Approximate	3 · Results and Discussion · Figure 1