Spectroscopy — Multimetal Incorporation into 2D Conductive Metal-Organic Framework Nanowires Enabling Excellent Electrocatalytic Oxidation of Benzylamine to Benzonitrile

4 measurement groups · 18 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

NiCoFe-CAT nanowire powder · Powder

Elemental spectra and mapping for Ni-CAT, NiCo-CAT, NiFe-CAT, and NiCoFe-CAT.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NiCoFe-CAT EDS Co atomic fraction	Co K At% 1.56	—	—	Caption Exact Reported	4 · Supporting Information · Figure S7
NiCoFe-CAT EDS Fe atomic fraction	Fe K At% 0.81	—	—	Caption Exact Reported	4 · Supporting Information · Figure S7
NiCoFe-CAT EDS Ni atomic fraction	Ni K At% 1.41	—	—	Caption Exact Reported	4 · Supporting Information · Figure S7

NiCoFe-CAT/AB/PVDF on carbon cloth working electrode · Electrode

Electrolyte solution after chronoamperometry at 1.45 V after five cycles.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
GC-MS product selectivity after five cycles	only BN was produced	—	—	Text Qualitative	7 · Results and Discussion · Figure S24

NiCoFe-CAT after 10 h BA electrooxidation · Electrode

NiCoFe-CAT after 10 h BA electrooxidation.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Post-BA Co3+ Co 2p binding energy	Co3+ at 780.4 eV	—	—	Text Exact Reported	7 · Results and Discussion · Figure S28
NiCoFe-CAT morphology after 10 h BA electrooxidation	slenderer nanowire morphology can still be maintained	—	—	Caption Qualitative	11 · Supporting Information · Figure S25
Post-BA Ni3+ Ni 2p binding energy	Ni3+ at 856.4 eV	—	—	Text Exact Reported	7 · Results and Discussion · Figure S27

NiCoFe-CAT nanowire powder · Powder

Survey and high-resolution XPS of Ni, Co, Fe, C, and O for M-CAT series.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co 2p binding-energy shift in NiCoFe-CAT	about 0.34 eV to higher energy	—	—	Text Approximate	5 · Results and Discussion · Figure 3c
Fe 2p binding-energy shift in NiCoFe-CAT	about 1.05 eV to lower binding energy	—	—	Text Approximate	5 · Results and Discussion · Figure 3d
Ni 2p binding-energy shift in NiCoFe-CAT	approximately 0.11 eV to higher energy	—	—	Text Approximate	5 · Results and Discussion · Figure 3b
Ni-CAT XPS Ni atomic ratio	Ni At% 1.2	—	—	SI Table Exact Reported	5 · Supporting Information · Table S1
NiCo-CAT XPS Co atomic ratio	Co At% 1.49	—	—	SI Table Exact Reported	5 · Supporting Information · Table S1
NiCo-CAT XPS Ni atomic ratio	Ni At% 1.92	—	—	SI Table Exact Reported	5 · Supporting Information · Table S1
NiCoFe-CAT XPS Co atomic ratio	Co At% 1.52	—	—	SI Table Exact Reported	5 · Supporting Information · Table S1
NiCoFe-CAT XPS Fe atomic ratio	Fe At% 1.20	—	—	SI Table Exact Reported	5 · Supporting Information · Table S1
NiCoFe-CAT XPS Ni atomic ratio	Ni At% 1.46	—	—	SI Table Exact Reported	5 · Supporting Information · Table S1
NiFe-CAT XPS Fe atomic ratio	Fe At% 0.97	—	—	SI Table Exact Reported	5 · Supporting Information · Table S1
NiFe-CAT XPS Ni atomic ratio	Ni At% 1.09	—	—	SI Table Exact Reported	5 · Supporting Information · Table S1