Electrical Transport — Controlling Film Formation and Host-Guest Interactions to Enhance the Thermoelectric Properties of Nickel-Nitrogen-Based 2D Conjugated Coordination Polymers

3 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-synthesised Ni-HATI-Me film · Thin Film

Conductivity monitored during exposure of films to ambient air.

Temperature: room temperature
Atmosphere: ambient air exposure
Geometry: film conductivity measurement
Context: guest adsorption/degradation context
Measurement source: p004 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HATI-Me initial conductivity increase on air exposure	about twice in the first 5 min	—	about	Text Approximate	p004 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2a
Ni-HAB/Ni-HATP/Ni-HATI-H conductivity after initial air exposure	reduced to 30-85% once (<5 min) exposed to ambient air	—	range 30-85%	Text Range	p004 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2a

Ni-HAB synthesis-screening products · Thin Film

Electrical conductivities of Ni-HAB films from Table S1 screening conditions.

Temperature: room temperature
Atmosphere: not specified
Geometry: 2-probe or 4-probe as listed in Table S1
Context: pristine Ni-HAB screening films; some products include powders/inhomogeneity
Measurement source: p008 · Synthesis · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HAB with 1.5 equiv Ni(acac)2 and 70-80 equiv NaOAc conductivity	0.34 without DMF; 0.1-0.44 with DMF co-solvent	—	range for DMF co-solvent	Caption Range	p005 · Synthesis · Figure S3
Ni-HAB with 1.5 equiv Ni(acac)2 and 6-35.5 equiv NaOAc conductivity	0.50-1.1	—	range	Caption Range	p006 · Synthesis · Figure S4
Ni-HAB with 6 equiv Ni(acac)2 and NaOAc conductivity	ca. 5	—	—	Caption Approximate	p006 · Synthesis · Figure S5
Ni-HAB with Ni(acac)2 and NH4OH as-synthesised 4pp conductivity range	13-52	—	range	Caption Range	p007 · Synthesis · Figure S6
Ni-HAB optimized Table S1 4-probe conductivity after annealingMarked as a best value within this paper	93 (4-probe)	—	—	SI Table Exact Reported	p008 · Synthesis · Table S1

annealed Ni-HAB film · Thin Film

Ni-HAB film after annealing in N2.

Temperature: room temperature
Atmosphere: N2 / inert measurement context
Geometry: 4pp film measurement; manual probe station for room-temperature measurements
Context: pristine degassed framework film
Measurement source: p003 · Synthesis and Characterizations

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HAB annealed 4pp conductivityMarked as a best value within this paper	93	—	—	Text Exact Reported	p003 · Synthesis and Characterizations