Thermoelectric — Controlling Film Formation and Host-Guest Interactions to Enhance the Thermoelectric Properties of Nickel-Nitrogen-Based 2D Conjugated Coordination Polymers

6 measurement groups · 18 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-synthesised Ni-HAB film · Thin Film

As-synthesised, N2-stored, and annealed Ni-HAB states compared in Figure 2c-e.

Temperature: room temperature
Atmosphere: as-synthesised with O2/H2O adsorbates; N2 storage; annealing at 125 C for 90 min
Geometry: four-parallel-electrode device / room-temperature thermoelectric setup
Context: pristine framework modulated by guest adsorbates
Measurement source: p004 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2c-e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HAB annealed Seebeck coefficient	about -15	—	visual estimate	Visual Estimate Approximate	p005 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2d
Ni-HAB annealed conductivity from treatment plot	about 90	—	visual estimate	Visual Estimate Approximate	p004 · Figure 2 · Figure 2c
Ni-HAB as-synthesised conductivity	about 50	—	visual estimate	Visual Estimate Approximate	p004 · Figure 2 · Figure 2c

as-synthesised Ni-HATI-H film · Thin Film

As-synthesised, N2-stored, and annealed Ni-HATI-H states compared in Figure 2c-e.

Temperature: room temperature
Atmosphere: as-synthesised with O2/H2O adsorbates; N2 storage; annealing at 125 C for 90 min
Geometry: four-parallel-electrode device / room-temperature thermoelectric setup
Context: pristine framework modulated by guest adsorbates
Measurement source: p005 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HATI-H annealed Seebeck coefficient	about +6	—	visual estimate	Visual Estimate Approximate	p005 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2d
Ni-HATI-H annealed conductivity	about 8	—	visual estimate	Visual Estimate Approximate	p005 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2c
Ni-HATI-H highest film conductivityMarked as a best value within this paper	10	—	—	Text Exact Reported	p004 · Synthesis and Characterizations · Figure 1c

as-synthesised Ni-HATI-Me film · Thin Film

As-synthesised, N2-stored, and annealed Ni-HATI-Me states compared in Figure 2c-e.

Temperature: room temperature
Atmosphere: as-synthesised with O2/H2O adsorbates; N2 storage; annealing at 125 C for 90 min
Geometry: four-parallel-electrode device / room-temperature thermoelectric setup
Context: pristine framework modulated by guest adsorbates
Measurement source: p005 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2c-e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HATI-Me as-synthesised Seebeck coefficient	about +120	—	visual estimate	Visual Estimate Approximate	p005 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2d
Ni-HATI-Me highest film conductivityMarked as a best value within this paper	9.0 x 10^-2	—	—	Text Exact Reported	p004 · Synthesis and Characterizations · Figure 1c

as-synthesised Ni-HATP film · Thin Film

As-synthesised, N2-stored, and annealed Ni-HATP states compared in Figure 2c-e.

Temperature: room temperature
Atmosphere: as-synthesised with O2/H2O adsorbates; N2 storage; annealing at 125 C for 90 min
Geometry: four-parallel-electrode device / room-temperature thermoelectric setup
Context: pristine framework modulated by guest adsorbates
Measurement source: p004 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2c-e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HATP annealed conductivity	about 120	—	visual estimate	Visual Estimate Approximate	p005 · Host-Guest Interaction-Modulated Thermoelectrics · Figure 2c
Ni-HATP as-synthesised conductivity	about 105	—	visual estimate	Visual Estimate Approximate	p004 · Figure 2 · Figure 2c
Ni-HATP annealed power factor from treatment plotMarked as a best value within this paper	about 9-10	—	visual estimate	Visual Estimate Approximate	p004 · Figure 2 · Figure 2e
Ni-HATP Seebeck coefficient under treatments	about -20 to -25	—	visual estimate and text approx	Figure Axis Approximate	p023 · Thermoelectric characterization and analysis · Figure S24

annealed Ni-HATP film · Thin Film

Annealed Ni-HATP films measured from about 100 to 300 K; used to test hopping, SLoT, Zabrodskii, and heterogeneous transport models.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HATP near-room-temperature small activation energy	7.0	—	—	Text Exact Reported	p007 · Transport Mechanism · Figure 4b
Ni-HATP conductivity reduction from room temperature to 100 K	little more than 30%	—	little more than	Text Approximate	p007 · Transport Mechanism · Figure 4a

annealed Ni-HATP film · Thin Film

Highest-performing Ni-HATP thin films; room-temperature thermoelectric measurements.

Temperature: room temperature
Atmosphere: nitrogen/high-vacuum degassed context depending on measurement
Geometry: room-temperature four-parallel-electrode device and Linseis Thin-Film Analyzer for temperature-dependent/thermal data
Context: pristine degassed framework film
Measurement source: p004 · Synthesis and Characterizations · Figures 1 and 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-HATP highest film conductivityMarked as a best value within this paper	2.0 x 10^2	—	—	Text Exact Reported	p004 · Synthesis and Characterizations · Figure 1c
Ni-HATP maximum power factorMarked as a best value within this paper	10	—	—	Text Exact Reported	p002 · Introduction
Ni-HATP room-temperature thermal conductivity	0.37	—	—	Text Exact Reported	p004 · Synthesis and Characterizations
Ni-HATP estimated ZTMarked as a best value within this paper	8.1 x 10^-3	—	—	Calculated From Reported Rounded Reported	p004 · Synthesis and Characterizations