Powder X-ray diffraction
Desolvated Cu[Ni(pdt)2] powder · Powder
PXRD patterns compared for Cu[Cu(pdt)2] and Cu[Ni(pdt)2] as prepared, after 120 degC vacuum treatments, and after iodine doping.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu[Cu(pdt)2] a lattice parameter | 6.8222(4) A | — | (4) | Text Exact Reported | 6 · X-ray diffraction · Figure S1 |
| Cu[Cu(pdt)2] c lattice parameter | 16.5165(16) A | — | (16) | Text Exact Reported | 6 · X-ray diffraction · Figure S1 |
| Cu[Cu(pdt)2] room-temperature conductivity cited from prior work | 1 x 10-4 S/cm | — | — | Text Rounded Reported | 1 · Main text |
| Cu[Cu(pdt)2] collapse on desolvation | Cu[Cu(pdt)2] collapses under desolvating conditions. | — | — | Qualitative Qualitative | 6 · X-ray diffraction · Figure S1 |
| Cu[Ni(pdt)2] a lattice parameter | 6.82870(30) A | — | (30) | Text Exact Reported | 6 · X-ray diffraction · Figure S1 |
| Cu[Ni(pdt)2] c lattice parameter | 16.2176(12) A | — | (12) | Text Exact Reported | 6 · X-ray diffraction · Figure S1 |
| Cu[Ni(pdt)2] structural stability after desolvation and I2 exposure | Cu[Ni(pdt)2] remains structurally stable after desolvation and after exposure to I2 vapour. | — | — | Qualitative Qualitative | 6 · X-ray diffraction · Figure S1 |
| PXRD space group assignment | P42/mmc (S. G. no. 131) | — | — | Text Exact Reported | 6 · X-ray diffraction · Figure S1 |