Other — Conductivity, doping, and redox chemistry of a microporous dithiolene-based metal-organic framework

3 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Desolvated Cu[Ni(pdt)2] powder · Powder

Elemental analysis of Cu[Ni(pdt)2] after desolvation compared with CuNiC8H4N4S4 formula.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Found carbon content for desolvated Cu[Ni(pdt)2]	C 21.99%	—	—	Text Exact Reported	3 · Cu[Ni(pdt)2] and Cu[Cu(pdt)2]
Found sulfur content for desolvated Cu[Ni(pdt)2]	S 27.30%	—	—	Text Exact Reported	3 · Cu[Ni(pdt)2] and Cu[Cu(pdt)2]

Cu[Ni(pdt)2] powder exposed to I2 vapour for gravimetry · Powder

100 mg Cu[Ni(pdt)2] exposed to the same I2 vapour stream, 23 mg/h, for 4 h.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Iodine stream mass rate	23 mg/h	—	—	Text Exact Reported	2 · Iodine uptake check
Iodine stream molar rate	approximately 1.5 umol/min	—	approximately	Text Approximate	4 · Doping and Conductivity Measurements
Weight increase after iodine vapour exposure	no significant weight increase	—	—	Qualitative Qualitative	2 · Iodine uptake check
Gravimetry sample mass	100 mg sample	—	—	Text Exact Reported	2 · Iodine uptake check

As-synthesised solvated Cu[Ni(pdt)2] powder · Powder

TGA of as-synthesised Cu[Ni(pdt)2] to evaluate guest loss below 120 degC.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Possible acetonitrile guest composition	Cu[Ni(pdt)2].1.7MeCN	—	possible composition	Text Approximate	7 · Thermal Gravimetry Analysis (TGA) · Figure S2
Possible water guest composition	Cu[Ni(pdt)2].3.8H2O	—	possible composition	Text Approximate	7 · Thermal Gravimetry Analysis (TGA) · Figure S2
TGA guest-loss mass loss	15 wt% complete below 120 degC	—	—	Text Rounded Reported	7 · Thermal Gravimetry Analysis (TGA) · Figure S2