Wu F., Fang W., Yang X. et al. · Journal of the Chinese Chemical Society · 2019 · 522-528
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Cu3(HHTP)2/GCE is selective for dopamine over ascorbic acid under the tested conditions.
Caveat: Selectivity is demonstrated for AA and DA in the reported concentration comparison, not for a broad interferent panel.
p004 (journal p.525) · 3.2 Electrochemical sensing of DA · Figure 3 · Linked to 2 structured results
The Cu3(HHTP)2/GCE sensor provides a wide dopamine linear range, low detection limit, stability, reproducibility and acceptable serum recovery.
Caveat: Serum applicability is supported by three spiked serum rows in SI Table S1; broader biological matrices are not tested.
p006 (journal p.527) · 4 Conclusions · Linked to 8 structured results
Cu3(HHTP)2/GCE gives acceptable dopamine recovery in spiked human serum samples, with recoveries of 99.5-105% and RSD values below 5%.
Caveat: Only three serum spike levels are reported.
SI p003 · Determination of DA in real sample · Table S1 · Linked to 6 structured results
PXRD confirmed successful synthesis of Cu3(HHTP)2 with in-plane and axial long-range order expected for covalently linked layered materials.
Caveat: No CIF or full structural refinement is provided in the assigned documents.
p003 (journal p.524) · 3.1 Characterization · Figure 1d · Linked to 4 structured results
The authors attribute the high conductivity and sensing response of Cu3(HHTP)2 to highly conjugated organic linkers and d9 Cu(II) centres, enabling long-range delocalised electrons and increased electron density.
Caveat: The paper does not report a first-hand electrical conductivity value for its Cu3(HHTP)2 sample.
p004 (journal p.525) · 3.2 Electrochemical sensing of DA · Linked to 2 structured results
The dopamine electrochemical reaction on Cu3(HHTP)2/GCE is diffusion-controlled because peak currents are proportional to the square root of scan speed.
Caveat: The extracted evidence is the authors' reported proportional trend; fitted slopes are not tabulated.
p005 (journal p.526) · 3.3 Optimization of condition and dynamic studies · Figure 5 · Linked to 1 structured result
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu3(HHTP)2Browse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu3(HHTP)2Cu(II) centres / Cu2+ nodes · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineTwo-dimensional pi-conjugated honeycomb framework with square-planar Cu coordination environments and layered PXRD order. | p001 (journal p.522) · Abstract |
| glassy carbon electrode | C | unknown · Model SystemBare conductive electrode support/control. | p002 (journal p.523) · 2.2 Apparatus |
| HKUST-1Browse family: HKUST-1 / Cu₃(BTC)₂ | Not specified | 3D · UnknownComparator MOF electrode modifier; synthesis and composition not described in this paper. | p004 (journal p.525) · 3.2 Electrochemical sensing of DA · Figure S2 referenced |
| ZIF-8Browse family: ZIF-8 / Zn(mIm)₂ | Not specified | 3D · UnknownComparator MOF electrode modifier; synthesis and composition not described in this paper. | p004 (journal p.525) · 3.2 Electrochemical sensing of DA · Figure S2 referenced |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| bare GCEresearch_0222__mat__mat_glassy_carbon | Electrode · Pristine Control · Model | Polished, rinsed in ethanol and deionized water, and dried in N2 before use.glassy carbon electrode | p003 (journal p.524) · 2.4 Preparation of the Cu3(HHTP)2/GCE |
| Cu3(HHTP)2/GCE modified electroderesearch_0222__mat__mat_cu3_hhtp2 | Electrode · Composite Sample · Composite | 5 uL aqueous Cu3(HHTP)2 suspension drop-cast onto polished GCE and dried at room temperature for 5 h.glassy carbon electrode | p003 (journal p.524) · 2.4 Preparation of the Cu3(HHTP)2/GCE |
| Cu3(HHTP)2 film on ITO-coated glassresearch_0222__mat__mat_cu3_hhtp2 | Thin Film · Pristine Control · Pristine Framework | Drop-cast suspension in water onto ITO-coated glass.indium-tin-oxide (ITO)-coated glass | p003 (journal p.524) · 3.1 Characterization of Cu3(HHTP)2 · Figure 1b |
| activated Cu3(HHTP)2 powderresearch_0222__mat__mat_cu3_hhtp2 | Powder · Target Sample · Pristine Framework | Washed, acetone-exchanged, evacuated, and heat-activated; isolated as black powder. | p003 (journal p.524) · 3.1 Characterization of Cu3(HHTP)2 · Figure 1a |
| HKUST-1/GCEresearch_0222__mat__mat_hkust1 | Electrode · Composite Sample · Composite | Comparator MOF-modified electrode; preparation details not given.glassy carbon electrode | SI p002 · Supporting Information · Figure S2 |
| ZIF-8/GCEresearch_0222__mat__mat_zif8 | Electrode · Composite Sample · Composite | Comparator MOF-modified electrode; preparation details not given.glassy carbon electrode | SI p002 · Supporting Information · Figure S2 |