Complete recipeSource: Both
Route 1: Solvothermal
p007 · Typical synthesis of K3Fe2[PcFe-O8]
Metal precursorsiron(II) acetate, 9.4 mg, 0.054 mmol
Linker precursorsPcFe-OH8, 20 mg, 0.029 mmol
SolventsN-methyl-2-pyrrolidone/H2O, 3 mL/1 mL v/v
Additivespotassium acetate (KOAc), 26 mg, 0.26 mmol
AtmosphereDegassed by freeze-pump-thaw three times; sealed under high vacuum; general reactions under vacuum/Schlenk line or nitrogen.
Temperature150
Time72
Work-upCooled to room temperature, filtrated, soaked in degassed H2O for 1 day, washed by acetone and filtration.
ActivationDried under vacuum at 40 C; for BET, powder was treated in a supercritical CO2 dryer for 5 days and activated at 80 C overnight.
Scalability contextSmall 25 mL tube solvothermal/vacuum-sealed route; reported yield 88.4%.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | PcFe-OH8 | 20 mg, 0.029 mmol | p007 · Typical synthesis of K3Fe2[PcFe-O8] |
| Metal Source | iron (II) acetate | 9.4 mg, 0.054 mmol | p007 · Typical synthesis of K3Fe2[PcFe-O8] |
| Additive | KOAc | 26 mg, 0.26 mmol | p007 · Typical synthesis of K3Fe2[PcFe-O8] |
| Solvent | N-methyl-2-pyrrolidone (NMP) | 3 mL | p007 · Typical synthesis of K3Fe2[PcFe-O8] |
| Solvent | H2O | 1 mL in reaction; degassed H2O soak for 1 day during workup | p007 · Typical synthesis of K3Fe2[PcFe-O8] |
| Solvent | acetone | washing solvent | p007 · Typical synthesis of K3Fe2[PcFe-O8] |