Measurement evidence
Conductive metal–organic framework with redox metal center as cathode for high rate performance lithium ion battery · Gu S., Bai Z., Majumder S. et al. · Journal of Power Sources · 2019 · 22-29
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Cu3(HHTP)2 cathode electrode · Electrode
Cu3(HHTP)2/PVDF cathode versus Li chip anode, Celgard 2400 separator, 1.0 M LiPF6 in EC:DMC 1:1 electrolyte; 1.7-3.5 V vs Li+/Li; 25 degC; rates 0.5, 1, 5, 10, 20C.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| battery test voltage window | 1.7-3.5 V versus Li+/Li | — | — | Text Range | 3 · 2.4. Fabrication of the electrodes and batteries |
Co3(HHTP)2 cathode electrode · Electrode
Co3(HHTP)2 cathode at 1C for different cycles.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Co3(HHTP)2 cathode capacity | no meaningful capacity | — | — | Caption Qualitative | 6 · Supplementary figures and tables · Fig. S6 |
| visual estimate of Co3(HHTP)2 charge-discharge capacity scale | less than about 0.4 mA h g-1 from Fig. S6 axis | — | visual estimate upper bound | Visual Estimate Uncertain | 6 · Supplementary figures and tables · Fig. S6 |
Cu3(HHTP)2 cathode electrode · Electrode
Voltage window 1.7-3.5 V vs Li/Li+; scan rate 0.2 mV s-1; several cycles shown.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| merged reduction peak after cycling | 2.81 V | — | — | Text Exact Reported | 6 · 3.3. Lithium ion insertion-desertion discussion · Fig. 5 |
| CV reversible redox peak potentials | 2.43, 2.72, 2.84 and 3.28 V vs Li/Li+ | — | — | Text Exact Reported | 6 · 3.3. Lithium ion insertion-desertion discussion · Fig. 5 |
| CV scan rate | 0.2 mV s-1 | — | — | Caption Exact Reported | 5 · Figure caption · Fig. 5 |
Cu3(HHTP)2 cathode electrode · Electrode
1C cycling for 100 cycles in main Fig. 3b; 500 cycles in SI Fig. S4.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| capacity retention after 500 cycles at 1C | about 50% | — | — | Text Approximate | 4 · 3.2. Discharge-charge performance · Fig. S4 |
| capacity decay rate over 500 cycles at 1C | 0.09% per cycle | — | — | Text Exact Reported | 4 · 3.2. Discharge-charge performance · Fig. S4 |
| activated reversible capacity at 1CMarked as a best value within this paper | about 95 mA h g-1 after about 20 cycles | — | — | Text Approximate | 4 · 3.2. Discharge-charge performance · Fig. 3b |
| capacity decay from cycle 60 to 100 at 1C | 8.1% | — | — | Text Exact Reported | 4 · 3.2. Discharge-charge performance · Fig. 3b |
| visual estimate of discharge capacity after 500 cycles at 1C | approximately 43 mA h g-1 from Fig. S4 axis | — | visual estimate from rendered SI figure | Visual Estimate Uncertain | 5 · Supplementary figures and tables · Fig. S4 |
| visual estimate of Coulombic efficiency during 1C 500-cycle test | approximately 99-100% for most cycles after initial activation | — | visual estimate from rendered SI figure | Visual Estimate Approximate | 5 · Supplementary figures and tables · Fig. S4 |
Cu3(HHTP)2 cathode electrode · Electrode
1C cycling between 1.7 and 3.5 V vs Li+/Li at room temperature; first, second, fifth, tenth and twentieth cycles plotted.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| first-cycle discharge capacity at 1C | about 105 mA h g-1 | — | — | Text Approximate | 4 · 3.2. Discharge-charge performance · Fig. 3a |
| open circuit voltage | about 3.0 V | — | — | Text Approximate | 4 · 3.2. Discharge-charge performance · Fig. 3a |
| Li:Cu intercalation ratio after activation | almost 100% (Li:Cu) | — | — | Text Approximate | 5 · 3.3. Lithium ion insertion-desertion discussion · Fig. 3a |
| second-cycle Coulombic efficiency | 69.2% | — | — | Text Exact Reported | 4 · 3.2. Discharge-charge performance · Fig. 3 |
| second-cycle discharge capacity at 1C | about 81 mA h g-1 | — | — | Text Approximate | 4 · 3.2. Discharge-charge performance · Fig. 3a |
Cu3(HHTP)2 cathode electrode · Electrode
Current rates from 0.5C to 20C; Fig. 6a rate stepping and Fig. 6b 500-cycle tests at different rates.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| capacity decay rate at 20CMarked as a best value within this paper | 0.023% per cycle | — | — | Text Exact Reported | 6 · 3.4. High C-rate capability · Fig. 6b |
| capacity retention at 20C after 500 cyclesMarked as a best value within this paper | more than 85% | — | — | Text Approximate | 6 · 3.4. High C-rate capability · Fig. 6b |
| visual estimate of final discharge capacity at 0.5C after 500 cycles | approximately 25-30 mA h g-1 from Fig. 6b axis | — | visual estimate | Visual Estimate Uncertain | 5 · Figure · Fig. 6b |
| visual estimate of final discharge capacity at 20C after 500 cycles | approximately 84-86 mA h g-1 from Fig. 6b axis | — | visual estimate | Visual Estimate Uncertain | 5 · Figure · Fig. 6b |
| capacity retained at 20C during rate test | about 85 mA h g-1 | — | — | Text Approximate | 6 · 3.4. High C-rate capability · Fig. 6a |
| maximum capacity during rate test at 1CMarked as a best value within this paper | 94.9 mA h g-1 | — | — | Text Exact Reported | 6 · 3.4. High C-rate capability · Fig. 6a |
| capacity recovery on returning to 1C | about 89 mA h g-1 | — | — | Text Approximate | 6 · 3.4. High C-rate capability · Fig. 6a |
| top capacity after activation across rates | top capacity after activation does not show obvious difference with current-rate variation | — | — | Caption Qualitative | 6 · Supplementary figures and tables · Fig. S7 |
Cu3(HHTP)2 cathode electrode · Electrode
Table S1 summarises MOF electrodes; only the present-study Cu3(HHTP)2 first-hand entry was extracted as evidence.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Table S1 present-study current densityMarked as a best value within this paper | 20C | — | — | SI Table Exact Reported | 8 · Supplementary figures and tables · Table S1 |
| Table S1 present-study cycle countMarked as a best value within this paper | 500 cycles | — | — | SI Table Exact Reported | 8 · Supplementary figures and tables · Table S1 |
| Table S1 present-study voltage window | 1.7-3.5 V vs Li/Li+ | — | — | SI Table Range | 8 · Supplementary figures and tables · Table S1 |