cMOF Evidence Base
Electrochemistry Application — Mixed proton-electron conductivity in a dynamic 3D metal-organic framework

Measurement evidence

Electrochemistry Application

Mixed proton-electron conductivity in a dynamic 3D metal-organic framework · Rambabu D., Goossens T., Bakuru V.R. et al. · Chem · 2025 · 102590

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

solid-electrode cyclic voltammetry

Voltammetry

Al-MOF solid-electrode CV composite · Electrode

Three-electrode Bio-Logic setup; GC working electrode composite; Ag/AgCl saturated KCl reference; graphite counter; 1 M H2SO4; 10 mV/s; 0.9-0 V vs Ag/AgCl for Al-MOF.

Atmosphere
aqueous 1 M H2SO4 electrolyte
Geometry
drop-cast MOF/SP/PTFE composite on glassy carbon electrode
Context
composite electrode containing pristine Al-MOF
Measurement source
p010 · CV · Figure 5C
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Reduction peak R10.55 +/- 0.01 V vs Ag/AgCl0.55 V vs Ag/AgCl+/- 0.01 VText
Exact Reported		p008 · Reversible redox behavior · Figure 5C
Reduction peak R20.38 V vs Ag/AgCl0.38 V vs Ag/AgCl—Text
Exact Reported		p008 · Reversible redox behavior · Figure 5C
Reduction peak R30.195 +/- 0.005 V vs Ag/AgCl0.195 V vs Ag/AgCl+/- 0.005 VText
Exact Reported		p008 · Reversible redox behavior · Figure 5C

solid-electrode cyclic voltammetry

Voltammetry

Fe-MOF solid-electrode CV composite · Electrode

Three-electrode Bio-Logic setup; GC working electrode composite; Ag/AgCl saturated KCl reference; graphite counter; 1 M H2SO4; 10 mV/s; 0.85-0.0 V vs Ag/AgCl for Fe-MOF.

Atmosphere
aqueous 1 M H2SO4 electrolyte
Geometry
drop-cast MOF/SP/PTFE composite on glassy carbon electrode
Context
composite electrode containing pristine Fe-MOF
Measurement source
p010 · CV · Figure 5C
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Main oxidation peak O10.605 +/- 0.005 V vs Ag/AgCl0.605 V vs Ag/AgCl+/- 0.005 VText
Exact Reported		p008 · Reversible redox behavior · Figure 5C
Oxidation peak O20.44 V vs Ag/AgCl0.44 V vs Ag/AgCl—Text
Exact Reported		p008 · Reversible redox behavior · Figure 5C
Oxidation peak O30.22 +/- 0.01 V vs Ag/AgCl0.22 V vs Ag/AgCl+/- 0.01 VText
Exact Reported		p008 · Reversible redox behavior · Figure 5C