Measurement evidence
Mixed proton-electron conductivity in a dynamic 3D metal-organic framework · Rambabu D., Goossens T., Bakuru V.R. et al. · Chem · 2025 · 102590
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
H12-Fe2-(DOBDP)3 (_d) · Powder
Oxidation with NOBF4 and reduction with NaBH3CN; FTIR tracks carbonyl band and XRD tracks framework stability.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Oxidation-induced C=O carbonyl FTIR band | 1659 cm^-1 | 1659 cm^-1 | — | Text Exact Reported | p008 · Reversible redox behavior · Figure 5B; Figure S25B |
H12-Fe2-(DOBDP)3.12H2O (_h) powder · Powder
TGA under argon/nitrogen heating; elemental C,H analysis used to estimate water content across hydration states.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Al _h observed TGA water loss | 19.7 wt% | 19.7 wt% | — | SI Table Exact Reported | p011 · Figure S6 · Figure S6B |
| Water content in Al _ph phase | 8 H2O | 8 H2O per formula unit | — | Table Exact Reported | p005 · Water sorption and structure dynamics · Table 1 |
| Water content in Al _sh phase | 15 H2O; remaining 6 water molecules cannot be located due to disorder | 15 H2O per formula unit | — | Table Approximate | p005 · Water sorption and structure dynamics · Table 1 |
| Water content in fully dehydrated MOF phases | 0 H2O | 0 H2O per formula unit | — | Table Exact Reported | p005 · Water sorption and structure dynamics · Table 1 |
| Water content in Fe/Al _h phases | 12 H2O | 12 H2O per formula unit | — | Table Exact Reported | p005 · Water sorption and structure dynamics · Table 1 |
| Thermal stability before framework decomposition | MOFs remain thermally stable up to ~280 deg C | 553.15 K | ~ | Text Approximate | p011 · Figure S6 discussion · Figure S6 |
| Fe _h observed TGA water loss | 18.6 wt% | 18.6 wt% | — | SI Table Exact Reported | p011 · Figure S6 · Figure S6B |
| Water content in Fe _pd phase | 3 H2O | 3 H2O per formula unit | — | Table Exact Reported | p005 · Water sorption and structure dynamics · Table 1 |
| Water content in Fe _ph phase | 7 H2O | 7 H2O per formula unit | — | Table Exact Reported | p005 · Water sorption and structure dynamics · Table 1 |
| Water content in Fe _sh phase | 21 H2O | 21 H2O per formula unit | — | Table Exact Reported | p005 · Water sorption and structure dynamics · Table 1 |
| In _h observed TGA water loss | 23.1 wt% | 23.1 wt% | — | SI Table Exact Reported | p011 · Figure S6 · Figure S6B |
| Sc _h observed TGA water loss | 25.4 wt% | 25.4 wt% | — | SI Table Exact Reported | p011 · Figure S6 · Figure S6B |
| Water content in Sc/In _h phases | 18 H2O | 18 H2O per formula unit | — | Table Exact Reported | p005 · Water sorption and structure dynamics · Table 1 |
| Water content in Sc/In _ph phases | 4 H2O | 4 H2O per formula unit | — | Table Exact Reported | p005 · Water sorption and structure dynamics · Table 1 |