Other — Lithium Ion Diffusion in a Metal-Organic Framework Mediated by an Ionic Liquid

Measurement evidence

Other

Lithium Ion Diffusion in a Metal-Organic Framework Mediated by an Ionic Liquid · Fujie K., Ikeda R., Otsubo K. et al. · Chemistry of Materials · 2015 · 7355-7361

3 measurement groups · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Differential scanning calorimetry (DSC), DSC3100SA

ELT-bulk · Unknown

Hermetically sealed in aluminium pans under dried argon; heated to 473 K, cooled to 153 K, then reheated to 473 K at 5 K min^-1.

Temperature
153-473
Atmosphere
dried argon during sealing
Geometry
aluminium DSC pan
Context
bulk lithium-doped ionic liquid control
Measurement source
2 · Experimental Section
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ELT-bulk glass transition peak temperatureendothermic peak at 192 KText
Exact Reported
3 · Results and Discussion · Figure 4

Differential scanning calorimetry (DSC), DSC3100SA

ELT@Z100 · Pellet

Hermetically sealed in aluminium pans under dried argon; heated to 473 K, cooled to 153 K, then reheated to 473 K at 5 K min^-1.

Temperature
153-473
Atmosphere
dried argon during sealing
Geometry
aluminium DSC pan
Context
guest-loaded ZIF-8
Measurement source
2 · Experimental Section
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ELT@Z100 broad endothermic heat-flow rangebroad and weak endothermic heat flow from 200 to 240 K; onset around 200 KText
Range
3 · Results and Discussion · Figure 4

Differential scanning calorimetry (DSC), DSC3100SA

ELT@Z75 · Pellet

Hermetically sealed in aluminium pans under dried argon; heated to 473 K, cooled to 153 K, then reheated to 473 K at 5 K min^-1.

Temperature
153-473
Atmosphere
dried argon during sealing
Geometry
aluminium DSC pan
Context
guest-loaded ZIF-8
Measurement source
2 · Experimental Section
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ELT@Z75 absence of ELT-bulk glass transition anomalyno heat anomaly appeared around 192 KText
Qualitative
3 · Results and Discussion · Figure 4