Synthesis · Lithium Ion Diffusion in a Metal-Organic Framework Mediated by an Ionic Liquid

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Vague recipeSource: Main

Route 1: Other

2 · Experimental Section

AdditivesEMI-TFSA and LiTFSA

Atmospherenot specified for initial mixing; glovebox used for later sample handling

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Electrolyte	EMI-TFSA	Not specified	2 · Experimental Section
Electrolyte	LiTFSA (lithium bis(trifluoromethylsulfonyl)amide)	Not specified	2 · Experimental Section

Partial recipeSource: Main

Route 2: Other

2 · Experimental Section

Metal precursorsactivated ZIF-8

Additives(EMI0.8Li0.2)TFSA prepared from EMI-TFSA and LiTFSA

Atmosphereglovebox

Timestored overnight after heating

Work-upMixed with activated ZIF-8 using a mortar and pestle.

ActivationZIF-8 activated at 423 K overnight under vacuum before loading.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	activated ZIF-8	Not specified	2 · Experimental Section
Electrolyte	(EMI0.8Li0.2)TFSA	0.57:1 molar ratio relative to activated ZIF-8 · 100% calculated volumetric pore occupancy	2 · Experimental Section

Partial recipeSource: Main

Route 3: Other

2 · Experimental Section

Metal precursorsactivated ZIF-8

Additives(EMI0.8Li0.2)TFSA prepared from EMI-TFSA and LiTFSA

Atmosphereglovebox

Timestored overnight after heating

Work-upMixed with activated ZIF-8 using a mortar and pestle.

ActivationZIF-8 activated at 423 K overnight under vacuum before loading.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	activated ZIF-8	Not specified	2 · Experimental Section
Electrolyte	(EMI0.8Li0.2)TFSA	0.42:1 molar ratio relative to activated ZIF-8 · 75% calculated volumetric pore occupancy	2 · Experimental Section

Partial recipeSource: Main

Route 4: Other

2 · Experimental Section

Metal precursorsactivated ZIF-8

AdditivesEMI-TFSA

Atmosphereglovebox

Timestored overnight after heating

Work-upMixed with activated ZIF-8 using a mortar and pestle.

ActivationZIF-8 activated at 423 K overnight under vacuum before loading.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	activated ZIF-8	Not specified	2 · Experimental Section
Electrolyte	EMI-TFSA	0.57:1 molar ratio relative to activated ZIF-8 · 100% calculated volumetric pore occupancy	2 · Experimental Section

Partial recipeSource: Main

Route 5: Other

2 · Experimental Section

Metal precursorsactivated ZIF-8

AdditivesEMI-TFSA

Atmosphereglovebox

Timestored overnight after heating

Work-upMixed with activated ZIF-8 using a mortar and pestle.

ActivationZIF-8 activated at 423 K overnight under vacuum before loading.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	activated ZIF-8	Not specified	2 · Experimental Section
Electrolyte	EMI-TFSA	0.42:1 molar ratio relative to activated ZIF-8 · 75% calculated volumetric pore occupancy	2 · Experimental Section

Complete recipeSource: Main

Route 6: Other

2 · Experimental Section

Metal precursorsZn(NO3)2.6H2O (1.10 g, 3.70 mmol)

Linker precursors2-methylimidazole (1.22 g, 14.8 mmol)

Solventsmethanol, 75 mL for zinc nitrate solution and 75 mL for linker/base solution

Additivestriethylamine (3.00 g, 29.7 mmol)

Atmosphereambient temperature during synthesis; vacuum for activation

Temperatureambient for 1 h synthesis; 149.85 C activation

Time1 h stirring; overnight activation

Work-upWhite precipitate collected by centrifugation and washed five times using methanol.

ActivationActivated at 423 K overnight under vacuum.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Zn(NO3)2.6H2O	1.10 g, 3.70 mmol	2 · Experimental Section
Linker	2-methylimidazole	1.22 g, 14.8 mmol	2 · Experimental Section
Base	triethylamine	3.00 g, 29.7 mmol	2 · Experimental Section
Solvent	methanol	150 mL total	2 · Experimental Section